Chemical reaction network theory

This article summarizes equations in the theory of waves.

Definitions

General fundamental quantities

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A wave can be longitudinal where the oscillations are parallel (or antiparallel) to the propagation direction, or transverse where the oscillations are perpendicular to the propagation direction. These oscillations are characterized by a periodically time-varying displacement in the parallel or perpendicular direction, and so the instantaneous velocity and acceleration are also periodic and time varying in these directions. But the wave profile (the apparent motion of the wave due to the successive oscillations of particles or fields about their equilibrium positions) propagates at the phase and group velocities parallel or antiparallel to the propagation direction, which is common to longitudinal and transverse waves. Below oscillatory displacement, velocity and acceleration refer to the kinematics in the oscillating directions of the wave - transverse or longitudinal (mathematical description is identical), the group and phase velocities are separate.

Quantity (common name/s)	(Common) symbol/s	SI units	Dimension
Number of wave cycles	N	dimensionless	dimensionless
(Oscillatory) displacement	Symbol of any quantity which varies periodically, such as h, x, y (mechanical waves), x, s, η (longitudinal waves) I, V, E, B, H, D (electromagnetism), u, U (luminal waves), ψ, Ψ, Φ (quantum mechanics). Most general purposes use y, ψ, Ψ. For generality here, A is used and can be replaced by any other symbol, since others have specific, common uses. $\mathbf{A}=A{\hat{\mathbf{e}}}_{\parallel }$ for longitudinal waves, $\mathbf{A}=A{\hat{\mathbf{e}}}_{\mathrm{\perp }}$ for transverse waves.	m	[L]
(Oscillatory) displacement amplitude	Any quantity symbol typically subscripted with 0, m or max, or the capitalized letter (if displacement was in lower case). Here for generality A0 is used and can be replaced.	m	[L]
(Oscillatory) velocity amplitude	V, v0, vm. Here v0 is used.	m s−1	[L][T]−1
(Oscillatory) acceleration amplitude	A, a0, am. Here a0 is used.	m s−2	[L][T]−2
Spatial position Position of a point in space, not necessarily a point on the wave profile or any line of propagation	d, r	m	[L]
Wave profile displacement Along propagation direction, distance travelled (path length) by one wave from the source point r0 to any point in space d (for longitudinal or transverse waves)	L, d, r $\mathbf{r}\equiv r{\hat{\mathbf{e}}}_{\parallel }\equiv \mathbf{d}-{\mathbf{r}}_0$	m	[L]
Phase angle	δ, ε, φ	rad	dimensionless

General derived quantities

Quantity (common name/s)	(Common) symbol/s	Defining equation	SI units	Dimension
Wavelength	λ	General definition (allows for FM): $\lambda =\mathrm{d}r/\mathrm{d}N$ For non-FM waves this reduces to: $\lambda =\mathrm{\Delta }r/\mathrm{\Delta }N$	m	[L]
Wavenumber, k-vector, Wave vector	k, σ	Two definitions are in use: $\mathbf{k}=(2\pi /\lambda ){\hat{\mathbf{e}}}_{\mathrm{\angle }}$ $\mathbf{k}=(1/\lambda ){\hat{\mathbf{e}}}_{\mathrm{\angle }}$	m−1	[L]−1
Frequency	f, ν	General definition (allows for FM): $f=\mathrm{d}N/\mathrm{d}t$ For non-FM waves this reduces to: $f=\mathrm{\Delta }N/\mathrm{\Delta }t$ In practice N is set to 1 cycle and t = T = time period for 1 cycle, to obtain the more useful relation: $f=1/T$	Hz = s−1	[T]−1
Angular frequency/ pulsatance	ω	$\omega =2\pi f=2\pi /T$	Hz = s−1	[T]−1
Oscillatory velocity	v, vt, v	Longitudinal waves: $\mathbf{v}={\hat{\mathbf{e}}}_{\parallel }(\partial A/\partial t)$ Transverse waves: $\mathbf{v}={\hat{\mathbf{e}}}_{\mathrm{\perp }}(\partial A/\partial t)$	m s−1	[L][T]−1
Oscillatory acceleration	a, at	Longitudinal waves: $\mathbf{a}={\hat{\mathbf{e}}}_{\parallel }({\partial }^{2}A/\partial t^2)$ Transverse waves: $\mathbf{a}={\hat{\mathbf{e}}}_{\mathrm{\perp }}({\partial }^{2}A/\partial t^2)$	m s−2	[L][T]−2
Path length difference between two waves	L, ΔL, Δx, Δr	$\mathbf{r}={\mathbf{r}}_2-{\mathbf{r}}_1$	m	[L]
Phase velocity	vp	General definition: ${\mathbf{v}}_{\mathrm{p}}={\hat{\mathbf{e}}}_{\parallel }(\mathrm{\Delta }r/\mathrm{\Delta }t)$ In practice reduces to the useful form: ${\mathbf{v}}_{\mathrm{p}}=\lambda f{\hat{\mathbf{e}}}_{\parallel }=(\omega /k){\hat{\mathbf{e}}}_{\parallel }$	m s−1	[L][T]−1
(Longitudinal) group velocity	vg	${\mathbf{v}}_{\mathrm{g}}={\hat{\mathbf{e}}}_{\parallel }(\partial \omega /\partial k)$	m s−1	[L][T]−1
Time delay, time lag/lead	Δt	$\mathrm{\Delta }t=t_2-t_1$	s	[T]
Phase difference	δ, Δε, Δϕ	$\mathrm{\Delta }\varphi ={\varphi }_2-{\varphi }_1$	rad	dimensionless
Phase	No standard symbol	$\mathbf{k}\cdot \mathbf{r}\mp \omega t+\varphi =2\pi N$ Physically; upper sign: wave propagation in +r direction lower sign: wave propagation in −r direction Phase angle can lag if: ϕ > 0 or lead if: ϕ < 0.	rad	dimensionless

Relation between space, time, angle analogues used to describe the phase:

$\frac{\mathrm{\Delta }r}{\lambda }=\frac{\mathrm{\Delta }t}{T}=\frac{\varphi }{2\pi }$

Modulation indices

Quantity (common name/s)	(Common) symbol/s	Defining equation	SI units	Dimension
AM index:	h, hAM	$h_{AM}=A/A_m$ A = carrier amplitude Am = peak amplitude of a component in the modulating signal	dimensionless	dimensionless
FM index:	hFM	$h_{FM}=\mathrm{\Delta }f/f_m$ Δf = max. deviation of the instantaneous frequency from the carrier frequency fm = peak frequency of a component in the modulating signal	dimensionless	dimensionless
PM index:	hPM	$h_{PM}=\mathrm{\Delta }\varphi$ Δϕ = peak phase deviation	dimensionless	dimensionless

Acoustics

Quantity (common name/s)	(Common) symbol/s	Defining equation	SI units	Dimension
Acoustic impedance	Z	$Z=\rho v$ v = speed of sound, ρ = volume density of medium	kg m−2 s−1	[M] [L]−2 [T]−1
Specific acoustic impedance	z	$z=ZS$ S = surface area	kg s−1	[M] [T]−1
Sound Level	β	$\beta =\left(\mathrm{d}\mathrm{B}\right)10\log \left|\frac{I}{I_0}\right|$	dimensionless	dimensionless

Equations

In what follows n, m are any integers (Z = set of integers); $n,m\in \mathbf{Z}$.

Standing waves

Physical situation	Nomenclature	Equations
Harmonic frequencies	fn = nth mode of vibration, nth harmonic, (n-1)th overtone	$f_n=\frac{v}{{\lambda }_n}=\frac{nv}{2L}=n{f}_1$

Propagating waves

Sound waves

Physical situation	Nomenclature	Equations
Average wave power	P0 = Sound power due to source	$⟨P⟩=\mu v{\omega }^2{x}_m^2/2$
Sound intensity	Ω = Solid angle	$I=P_0/(\mathrm{\Omega }{r}^2)$ $I=P/A=\rho v{\omega }^2{s}_m^2/2$
Acoustic beat frequency	f1, f2 = frequencies of two waves (nearly equal amplitudes)	$f_{\mathrm{b}\mathrm{e}\mathrm{a}\mathrm{t}}=|f_2-f_1|$
Doppler effect for mechanical waves	V = speed of sound wave in medium f0 = Source frequency fr = Receiver frequency v0 = Source velocity vr = Receiver velocity	$f_r=f_0\frac{V\pm v_r}{v\mp v_0}$ upper signs indicate relative approach,lower signs indicate relative recession.
Mach cone angle (Supersonic shockwave, sonic boom)	v = speed of body v = local speed of sound θ = angle between direction of travel and conic evelope of superimposed wavefronts	$\sin \theta =\frac{v}{v_s}$
Acoustic pressure and displacement amplitudes	p0 = pressure amplitude s0 = displacement amplitude v = speed of sound ρ = local density of medium	$p_0=\left(v\rho \omega \right)s_0$
Wave functions for sound		Acoustic beats $s=[2s_0\cos \left({\omega }^{\prime }t\right)]\cos \left(\omega t\right)$ Sound displacement function $s=s_0\cos (kr-\omega t)$ Sound pressure-variation $p=p_0\sin (kr-\omega t)$

Gravitational waves

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Gravitational radiation for two orbiting bodies in the low-speed limit.

Physical situation	Nomenclature	Equations
Radiated power	P = Radiated power from system, t = time, r = separation between centres-of-mass m1, m2 = masses of the orbiting bodies	$P=\frac{\mathrm{d}E}{\mathrm{d}t}=-\frac{32}{5}\frac{G^4}{c^5}\frac{(m_1{m}_2{)}^2(m_1+m_2)}{r^5}$
Orbital radius decay		$\frac{\mathrm{d}r}{\mathrm{d}t}=-\frac{64}{5}\frac{G^3}{c^5}\frac{(m_1{m}_2)(m_1+m_2)}{r^3}$
Orbital lifetime	r0 = initial distance between the orbiting bodies	$t=\frac{5}{256}\frac{c^5}{G^3}\frac{r_0^4}{(m_1{m}_2)(m_1+m_2)}$

Superposition, interference, and diffraction

Physical situation	Nomenclature	Equations
Principle of superposition	N = number of waves	$y_{\mathrm{n}\mathrm{e}\mathrm{t}}=\sum _{i=1}^N{y}_i$
Resonance	ωd = driving angular frequency (external agent) ωnat = natural angular frequency (oscillator)	${\omega }_d={\omega }_{\mathrm{n}\mathrm{a}\mathrm{t}}$
Phase and interference	Δr = path length difference φ = phase difference between any two successive wave cycles	$\frac{\mathrm{\Delta }r}{\lambda }=\frac{\mathrm{\Delta }t}{T}=\frac{\varphi }{2\pi }$ Constructive interference $n=\frac{\lambda }{\mathrm{\Delta }x}$ Destructive interference $n+\frac{1}{2}=\frac{\lambda }{\mathrm{\Delta }x}$

Wave propagation

A common misconception occurs between phase velocity and group velocity (analogous to centres of mass and gravity). They happen to be equal in non-dispersive media. In dispersive media the phase velocity is not necessarily the same as the group velocity. The phase velocity varies with frequency.

The phase velocity is the rate at which the phase of the wave propagates in space.

The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the profile of the wave amplitudes; all transverse displacements are bound by the envelope profile.

Intuitively the wave envelope is the "global profile" of the wave, which "contains" changing "local profiles inside the global profile". Each propagates at generally different speeds determined by the important function called the Dispersion Relation. The use of the explicit form ω(k) is standard, since the phase velocity ω/k and the group velocity dω/dk usually have convenient representations by this function.

Physical situation	Nomenclature	Equations
Idealized non-dispersive media	p = (any type of) Stress or Pressure, ρ = Volume Mass Density, F = Tension Force, μ = Linear Mass Density of medium	$v=\sqrt{\frac{p}{\rho }}=\sqrt{\frac{F}{\mu }}$
Dispersion relation		Implicit form $D(\omega ,k)=0$ Explicit form $\omega =\omega \left(k\right)$
Amplitude modulation, AM		$A=A\left(t\right)$
Frequency modulation, FM		$f=f\left(t\right)$

General wave functions

Wave equations

Physical situation	Nomenclature	Wave equation	General solution/s
Non-dispersive Wave Equation in 3d	A = amplitude as function of position and time	${\mathrm{\nabla }}^{2}A=\frac{1}{v_{\parallel }^2}\frac{{\partial }^{2}A}{\partial t^2}$	$A(\mathbf{r},t)=A(x-v_{\parallel }t)$
Exponentially damped waveform	A0 = Initial amplitude at time t = 0 b = damping parameter		$A=A_0{e}^{-bt}\sin (kx-\omega t+\varphi )$
Korteweg–de Vries equation	α = constant	$\frac{\partial y}{\partial t}+\alpha y\frac{\partial y}{\partial x}+\frac{{\partial }^{3}y}{\partial x^3}=0$	$A(x,t)=\frac{3v_{\parallel }}{\alpha }{\mathrm{s}\mathrm{e}\mathrm{c}\mathrm{h}}^2\left[\frac{\sqrt{v_{\parallel }}}{2}(x-v_{\parallel }t)\right]$

Sinusoidal solutions to the 3d wave equation

N different sinusoidal waves

Complex amplitude of wave n
$A_n=\left|A_n\right|e^{i({\mathbf{k}}_{\mathrm{n}}\cdot \mathbf{r}-{\omega }_{n}t+{\varphi }_n)}$

Resultant complex amplitude of all N waves
$A=\sum _{n=1}^N{A}_n$

Modulus of amplitude
$A=\sqrt{A{A}^{*}}=\sqrt{\sum _{n=1}^N\sum _{m=1}^N\left|A_n\right|\left|A_m\right|\cos [({\mathbf{k}}_n-{\mathbf{k}}_m)\cdot \mathbf{r}+({\omega }_n-{\omega }_m)t+({\varphi }_n-{\varphi }_m)]}$

The transverse displacements are simply the real parts of the complex amplitudes.

1 dimensional corollaries for two sinusoidal waves

The following may be deduced by applying the principle of superposition to two sinusoidal waves, using trigonometric identities. The angle addition and sum-to-product trigonometric formulae are useful; in more advanced work complex numbers and fourier series and transforms are used.

Wavefunction	Nomenclature	Superposition	Resultant
Standing wave		$\begin{array}{rl}{y}_1+y_2& =A\sin (kx-\omega t)\\ & +A\sin (kx+\omega t)\end{array}$	$y=A\sin \left(kx\right)\cos \left(\omega t\right)$
Beats	$⟨\omega ⟩=\frac{{\omega }_1+{\omega }_2}{2}$ $⟨k⟩=\frac{k_1+k_2}{2}$ $\mathrm{\Delta }\omega ={\omega }_1-{\omega }_2$ $\mathrm{\Delta }k=k_1-k_2$	$\begin{array}{rl}{y}_1+y_2& =A\sin (k_{1}x-{\omega }_{1}t)\\ & +A\sin (k_{2}x+{\omega }_{2}t)\end{array}$	$y=2A\sin (⟨k⟩x-⟨\omega ⟩t)\cos (\frac{\mathrm{\Delta }k}{2}x-\frac{\mathrm{\Delta }\omega }{2}t)$
Coherent interference		$\begin{array}{rl}{y}_1+y_2& =A\sin (kx-\omega t)\\ & +A\sin (kx+\omega t+\varphi )\end{array}$	$y=2A\cos \left(\frac{\varphi }{2}\right)\sin (kx-\omega t+\frac{\varphi }{2})$

See also

• SI electromagnetism units
• Defining equation (physical chemistry)
• List of equations in classical mechanics
• List of relativistic equations
• List of equations in fluid mechanics
• List of equations in gravitation
• List of photonics equations
• List of equations in quantum mechanics
• List of equations in nuclear and particle physics

Footnotes

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Sources

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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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Further reading

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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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