Russo–Dye theorem: Difference between revisions
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{{Distinguish|chemical ionization}} | |||
'''Chemi-ionization''' is the formation of an [[ion]] through the reaction of a gas phase [[atom]] or [[molecule]] with an atom or molecule in an [[excited state]].<ref>{{GoldBookRef|title=chemi-ionization|file= C01044}} C01044</ref><ref name=Klucharev1993>{{citation | last = Klucharev | first = A. N. | year = 1993 | title = Chemi-ionization processes | journal = Physics-Uspekhi | volume = 36 | pages = 486 | doi = 10.1070/PU1993v036n06ABEH002162 |bibcode = 1993PhyU...36..486K | issue = 6 }}</ref> | |||
==Reactions== | |||
Chemi-ionization can be represented by | |||
:<math>G^* + M \to M^{+\bullet} + e^- + G</math> | |||
where G is the excited state species (indicated by the superscripted asterisk), and M is the species that is ionized by the loss of an [[electron]] to form the [[Radical (chemistry)|radical]] [[cation]] (indicated by the superscripted "plus-dot"). | |||
==See also== | |||
*[[Penning ionization]] | |||
*[[Associative ionization]] | |||
*[[Charge-exchange ionization]] | |||
==References== | |||
{{Reflist}} | |||
{{atomic-physics-stub}} | |||
[[Category:Ion source]] | |||
Revision as of 09:53, 21 April 2013
Template:Distinguish Chemi-ionization is the formation of an ion through the reaction of a gas phase atom or molecule with an atom or molecule in an excited state.[1][2]
Reactions
Chemi-ionization can be represented by
where G is the excited state species (indicated by the superscripted asterisk), and M is the species that is ionized by the loss of an electron to form the radical cation (indicated by the superscripted "plus-dot").
See also
References
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- ↑ Template:GoldBookRef C01044
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