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{{continuum mechanics|cTopic=[[Solid mechanics]]}}
In [[continuum mechanics]], a '''Mooney–Rivlin solid'''<ref name=Mooney>Mooney, M., 1940, ''A theory of large elastic deformation'', Journal of Applied Physics, 11(9), pp. 582-592.</ref><ref name=Rivlin>Rivlin, R. S., 1948, ''Large elastic deformations of isotropic materials. IV. Further developments of the general theory'', Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 241(835), pp. 379-397.</ref> is a [[hyperelastic material]] model where the [[strain energy density function]]  <math>W\,</math> is a linear combination of two [[Invariants of tensors|invariants]] of the [[finite strain theory|left Cauchy–Green deformation tensor]] <math>\boldsymbol{B}</math>. The model was proposed by [[Melvin Mooney]] in 1940 and expressed in terms of invariants by [[Ronald Rivlin]] in 1948.
 
The strain energy density function for an [[incompressible]] Mooney–Rivlin material is<ref>Boulanger, P. and Hayes, M. A., 2001, '' Finite amplitude waves in Mooney–Rivlin and Hadamard materials'', in '''Topics in Finite Elasticity''', ed. M. A Hayes and G. Soccomandi, International Center for Mechanical Sciences.</ref><ref>C. W. Macosko, 1994, '''Rheology: principles, measurement and applications''', VCH Publishers, ISBN 1-56081-579-5.</ref>
 
:<math>W = C_{1} (\overline{I}_1-3) + C_{2} (\overline{I}_2-3), \, </math>
 
where <math>C_{1}</math> and <math>C_{2}</math> are empirically determined material constants, and <math>I_1</math> and <math>I_2</math> are the first and the second [[Invariants of tensors|invariant]] of the [[Unimodular matrix|unimodular]] component of the [[finite strain theory|left Cauchy–Green deformation tensor]]:<ref>The characteristic polynomial of the linear operator corresponding to the second rank three-dimensional Finger tensor (also called the left Cauchy–Green deformation tensor) is usually written
:<math>p_B (\lambda) = \lambda^3 - a_1 \, \lambda^2 + a_2 \, \lambda - a_3 \, </math>
In this article, the [[trace (linear algebra)|trace]] <math>a_1</math> is written <math>I_1</math>, the next coefficient <math>a_2</math> is written <math>I_2</math>, and the determinant <math>a_3</math> would be written <math>I_3</math>.</ref>
:<math>
  \begin{align}
    \bar{I}_1 & = J^{-2/3}~I_1 ~;~~ I_1 = \lambda_1^2 +  \lambda_2 ^2+ \lambda_3 ^2 ~;~~ J = \det(\boldsymbol{F}) \\
    \bar{I}_2 & = J^{-4/3}~I_2 ~;~~ I_2 = \lambda_1^2 \lambda_2^2 +  \lambda_2^2 \lambda_3^2 + \lambda_3^2 \lambda_1^2
  \end{align}
</math>
where <math>\boldsymbol{F}</math> is the [[deformation gradient]]. For an [[incompressible]] material, <math>J=1</math>.
 
==Derivation==
The Mooney–Rivlin model is a special case of the '''generalized Rivlin model''' (also called [[Polynomial (hyperelastic model)|polynomial hyperelastic model]]<ref name=Bower>{{cite book
|title=Applied Mechanics of Solids
|last=Bower |first=Allan
|year=2009
|publisher=CRC Press
|isbn=1-4398-0247-5
|url=http://solidmechanics.org/
|accessdate=January 2010}}</ref>) which has the form
:<math>
  W = \sum_{p,q = 0}^N C_{pq} (\bar{I}_1 - 3)^p~(\bar{I}_2 - 3)^q +
      \sum_{m = 1}^M D_m~(J-1)^{2m}
</math>
with <math>C_{00} = 0</math> where <math>C_{pq}</math> are material constants related to the distortional response and <math>D_m</math> are material constants related to the volumetric response. For a [[compressible]] Mooney–Rivlin material <math>N = 1, C_{01} = C_2, C_{11} = 0, C_{10} = C_1, M=1</math> and we have
:<math>
  W = C_{01}~(\bar{I}_2 - 3) + C_{10}~(\bar{I}_1 - 3) + D_1~(J-1)^2
</math>
If <math>C_{01} = 0</math> we obtain a [[neo-Hookean solid]], a special case of a '''Mooney–Rivlin solid'''.
 
For consistency with [[linear elasticity]] in the limit of [[infinitesimal strain theory|small strains]], it is necessary that
:<math>
    \kappa = 2 \cdot D_1 ~;~~ \mu = 2~(C_{01} + C_{10})
</math>
where <math>\kappa</math> is the [[bulk modulus]] and <math>\mu</math> is the [[shear modulus]].
 
==Cauchy stress in terms of strain invariants and deformation tensors==
The [[stress (physics)|Cauchy stress]] in a [[compressible]] hyperelastic material with a stress free reference configuration is given by
:<math>
  \boldsymbol{\sigma} = \cfrac{2}{J}\left[\cfrac{1}{J^{2/3}}\left(\cfrac{\partial{W}}{\partial \bar{I}_1} + \bar{I}_1~\cfrac{\partial{W}}{\partial \bar{I}_2}\right)\boldsymbol{B} -
  \cfrac{1}{J^{4/3}}~\cfrac{\partial{W}}{\partial \bar{I}_2}~\boldsymbol{B} \cdot\boldsymbol{B} \right]  + \left[\cfrac{\partial{W}}{\partial J} -
\cfrac{2}{3J}\left(\bar{I}_1~\cfrac{\partial{W}}{\partial \bar{I}_1} + 2~\bar{I}_2~\cfrac{\partial{W}}{\partial \bar{I}_2}\right)\right]~\boldsymbol{\mathit{1}}
</math>
For a compressible Mooney–Rivlin material,
:<math>
  \cfrac{\partial{W}}{\partial \bar{I}_1} = C_1 ~;~~ \cfrac{\partial{W}}{\partial \bar{I}_2} = C_2 ~;~~ \cfrac{\partial{W}}{\partial J} = 2D_1(J-1)
</math>
Therefore, the Cauchy stress in a compressible Mooney–Rivlin material is given by
:<math>
  \boldsymbol{\sigma} = \cfrac{2}{J}\left[\cfrac{1}{J^{2/3}}\left(C_1 + \bar{I}_1~C_2\right)\boldsymbol{B} -
  \cfrac{1}{J^{4/3}}~C_2~\boldsymbol{B} \cdot\boldsymbol{B} \right] + \left[2D_1(J-1)-
\cfrac{2}{3J}\left(C_1\bar{I}_1 + 2C_2\bar{I}_2~\right)\right]\boldsymbol{\mathit{1}}
  </math>
It can be shown, after some algebra, that the [[pressure]] is given by
:<math>
  p := -\tfrac{1}{3}\,\text{tr}(\boldsymbol{\sigma}) = -\frac{\partial W}{\partial J} = -2 D_1 (J-1) \,.
</math>
The stress can then be expressed in the form
:<math>
  \boldsymbol{\sigma} = \cfrac{1}{J}\left[-p~\boldsymbol{\mathit{1}} + \cfrac{2}{J^{2/3}}\left(C_1 + \bar{I}_1~C_2\right)\boldsymbol{B} -
  \cfrac{2}{J^{4/3}}~C_2~\boldsymbol{B}\cdot\boldsymbol{B}  -\cfrac{2}{3}\left(C_1\,\bar{I}_1 + 2C_2\,\bar{I}_2\right)\boldsymbol{\mathit{1}}\right] \,.
</math>
The above equation is often written as
:<math>
  \boldsymbol{\sigma} = \cfrac{1}{J}\left[-p~\boldsymbol{\mathit{1}} + 2\left(C_1 + \bar{I}_1~C_2\right)\bar{\boldsymbol{B}} -
  2~C_2~\bar{\boldsymbol{B}}\cdot\bar{\boldsymbol{B}} -\cfrac{2}{3}\left(C_1\,\bar{I}_1 + 2C_2\,\bar{I}_2\right)\boldsymbol{\mathit{1}}\right] \quad \text{where} \quad
  \bar{\boldsymbol{B}} = J^{-2/3}\,\boldsymbol{B} \,.
</math>
For an '''incompressible''' Mooney–Rivlin material with <math> J = 1</math>
:<math>
  \boldsymbol{\sigma} =  2\left(C_1 + I_1~C_2\right)\boldsymbol{B} -
  2C_2~\boldsymbol{B}\cdot\boldsymbol{B} -\cfrac{2}{3}\left(C_1\,\bar{I}_1 + 2C_2\,\bar{I}_2\right)\boldsymbol{\mathit{1}}\,.
</math>
Note that if <math>J=1</math> then
:<math>
  \det(\boldsymbol{B}) = \det(\boldsymbol{F})\det(\boldsymbol{F}^T) = 1
</math>
Then, from the [[Cayley-Hamilton theorem]],
:<math>
  \boldsymbol{B}^{-1} = \boldsymbol{B}\cdot\boldsymbol{B} - I_1~\boldsymbol{B} + I_2~\boldsymbol{\mathit{1}}
</math>
Hence, the Cauchy stress can be expressed as
:<math>
  \boldsymbol{\sigma} = -p^{*}~\boldsymbol{\mathit{1}} + 2 C_1~\boldsymbol{B} - 2C_2~\boldsymbol{B}^{-1}
</math>
where <math>p^{*} := \tfrac{2}{3}(C_1~I_1 - C_2~I_2). \, </math>
 
==Cauchy stress in terms of principal stretches==
In terms of the [[finite strain theory|principal stretches]], the Cauchy stress differences for an '''incompressible''' hyperelastic material are given by
:<math>
  \sigma_{11} - \sigma_{33} = \lambda_1~\cfrac{\partial{W}}{\partial \lambda_1} - \lambda_3~\cfrac{\partial{W}}{\partial \lambda_3} ~;~~
  \sigma_{22} - \sigma_{33} = \lambda_2~\cfrac{\partial{W}}{\partial \lambda_2} - \lambda_3~\cfrac{\partial{W}}{\partial \lambda_3}
</math>
For an '''incompressible''' Mooney-Rivlin material,
:<math>
  W = C_1(\lambda_1^2 +  \lambda_2 ^2+ \lambda_3 ^2 -3) + C_2(\lambda_1^2 \lambda_2^2 +  \lambda_2^2 \lambda_3^2 + \lambda_3^2 \lambda_1^2 -3) ~;~~ \lambda_1\lambda_2\lambda_3 = 1
</math>
Therefore,
:<math>
  \lambda_1\cfrac{\partial{W}}{\partial \lambda_1} = 2C_1\lambda_1^2 + 2C_2\lambda_1^2(\lambda_2^2+\lambda_3^2) ~;~~
  \lambda_2\cfrac{\partial{W}}{\partial \lambda_2} = 2C_1\lambda_2^2 + 2C_2\lambda_2^2(\lambda_1^2+\lambda_3^2)  ~;~~
  \lambda_3\cfrac{\partial{W}}{\partial \lambda_3} = 2C_1\lambda_3^2 + 2C_2\lambda_3^2(\lambda_1^2+\lambda_2^2)
</math>
Since <math>\lambda_1\lambda_2\lambda_3=1</math>. we can write
:<math>
  \begin{align}
  \lambda_1\cfrac{\partial{W}}{\partial \lambda_1} & = 2C_1\lambda_1^2 + 2C_2\left(\cfrac{1}{\lambda_3^2}+\cfrac{1}{\lambda_2^2}\right) ~;~~
  \lambda_2\cfrac{\partial{W}}{\partial \lambda_2}  = 2C_1\lambda_2^2 + 2C_2\left(\cfrac{1}{\lambda_3^2}+\cfrac{1}{\lambda_1^2}\right) \\
  \lambda_3\cfrac{\partial{W}}{\partial \lambda_3} & = 2C_1\lambda_3^2 + 2C_2\left(\cfrac{1}{\lambda_2^2}+\cfrac{1}{\lambda_1^2}\right)
  \end{align}
</math>
Then the expressions for the Cauchy stress differences become
:<math>
  \sigma_{11}-\sigma_{33} = 2C_1(\lambda_1^2-\lambda_3^2) - 2C_2\left(\cfrac{1}{\lambda_1^2}-\cfrac{1}{\lambda_3^2}\right)~;~~
  \sigma_{22}-\sigma_{33} = 2C_1(\lambda_2^2-\lambda_3^2) - 2C_2\left(\cfrac{1}{\lambda_2^2}-\cfrac{1}{\lambda_3^2}\right)
</math>
 
==Uniaxial extension==
For the case of an incompressible Mooney–Rivlin material under uniaxial elongation, <math>\lambda_1 = \lambda\,</math> and <math>\lambda_2 = \lambda_3 = 1/\sqrt{\lambda}</math>. Then the [[stress (physics)|true stress]] (Cauchy stress) differences can be calculated as:
:<math>
  \begin{align}
  \sigma_{11}-\sigma_{33} & = 2C_1\left(\lambda^2-\cfrac{1}{\lambda}\right) -2C_2\left(\cfrac{1}{\lambda^2} - \lambda\right)\\
  \sigma_{22}-\sigma_{33} & =  0
    \end{align}
</math>
 
===Simple tension===
[[File:Mooney-Rivlin.svg|thumb|380px|right|Comparison of experimental results (dots) and predictions for [[Hooke's law]](1, blue line), [[neo-Hookean solid]](2, red line) and Mooney–Rivlin solid models(3, green line)]]
In the case of simple tension, <math>\sigma_{22} = \sigma_{33} = 0 </math>. Then we can write
:<math>
  \sigma_{11} = \left(2C_1 + \cfrac {2C_2} {\lambda} \right) \left( \lambda^2 - \cfrac{1}{\lambda} \right)
</math>
In alternative notation, where the Cauchy stress is written as <math>\boldsymbol{T}</math> and the stretch as <math>\alpha</math>, we can write
:<math>T_{11} = \left(2C_1 + \frac {2C_2} {\alpha} \right) \left( \alpha^2 - \alpha^{-1} \right)</math>
and the [[engineering stress]] (force per unit reference area) for an incompressible Mooney–Rivlin material under simple tension can be calculated using
<math>T_{11}^{\mathrm{eng}} = T_{11}\alpha_2\alpha_3 = \cfrac{T_{11}}{\alpha} </math>. Hence
:<math>
  T_{11}^{\mathrm{eng}}= \left(2C_1 + \frac {2C_2} {\alpha} \right) \left( \alpha - \alpha^{-2} \right)
</math>
If we define
:<math>
  T^{*}_{11} := \cfrac{T_{11}^{\mathrm{eng}}}{\alpha - \alpha^{-2}} ~;~~ \beta := \cfrac{1}{\alpha}
</math>
then
:<math>
  T^{*}_{11} = 2C_1 + 2C_2\beta ~.
</math>
The slope of the <math> T^{*}_{11}</math> versus <math>\beta</math> line gives the value of <math>C_2</math> while the intercept with the <math>T^{*}_{11}</math> axis gives the value of <math>C_1</math>.  The Mooney–Rivlin solid model usually fits experimental data better than [[Neo-Hookean solid]] does, but requires an additional empirical constant.
 
==Equibiaxial tension==
In the case of equibiaxial tension, the principal stretches are <math>\lambda_1 = \lambda_2 = \lambda</math>.  If, in addition, the material is incompressible then <math>\lambda_3 = 1/\lambda^2</math>.  The Cauchy stress differences may therefore be expressed as
:<math>
  \sigma_{11}-\sigma_{33} = \sigma_{22}-\sigma_{33} = 2C_1\left(\lambda^2-\cfrac{1}{\lambda^4}\right) - 2C_2\left(\cfrac{1}{\lambda^2} - \lambda^4\right)
</math>
The equations for equibiaxial tension are equivalent to those governing uniaxial compression.
 
==Pure shear==
A pure shear deformation can be achieved by applying stretches of the form <ref name=Ogden>Ogden, R. W., 1984, '''Nonlinear elastic deformations''', Dover</ref>
:<math>
  \lambda_1 = \lambda ~;~~ \lambda_2 = \cfrac{1}{\lambda} ~;~~ \lambda_3 = 1
</math>
The Cauchy stress differences for pure shear may therefore be expressed as
:<math>
  \sigma_{11} - \sigma_{33} = 2C_1(\lambda^2-1) - 2C_2\left(\cfrac{1}{\lambda^2}-1\right) ~;~~
  \sigma_{22} - \sigma_{33} = 2C_1\left(\cfrac{1}{\lambda^2} -1\right) - 2C_2(\lambda^2 -1)
</math>
Therefore
:<math>
  \sigma_{11} - \sigma_{22} = 2(C_1+C_2)\left(\lambda^2 - \cfrac{1}{\lambda^2}\right)
</math>
For a pure shear deformation
:<math>
  I_1 = \lambda_1^2 + \lambda_2^2 + \lambda_3^2 = \lambda^2 + \cfrac{1}{\lambda^2} + 1 ~;~~
  I_2 = \cfrac{1}{\lambda_1^2} + \cfrac{1}{\lambda_2^2} + \cfrac{1}{\lambda_3^2} = \cfrac{1}{\lambda^2} + \lambda^2 + 1
</math>
Therefore <math>I_1 = I_2</math>.
 
==Simple shear==
The deformation gradient for a simple shear deformation has the form<ref name=Ogden/>
:<math>
  \boldsymbol{F} = \boldsymbol{1} + \gamma~\mathbf{e}_1\otimes\mathbf{e}_2
</math>
where <math>\mathbf{e}_1,\mathbf{e}_2</math> are reference orthonormal basis vectors in the plane of deformation and the shear deformation is given by
:<math>
  \gamma = \lambda - \cfrac{1}{\lambda} ~;~~ \lambda_1 = \lambda ~;~~ \lambda_2 = \cfrac{1}{\lambda} ~;~~ \lambda_3 = 1
</math>
In matrix form, the deformation gradient and the left Cauchy-Green deformation tensor may then be expressed as
:<math>
  \boldsymbol{F} = \begin{bmatrix} 1 & \gamma & 0 \\ 0 & 1 & 0 \\ 0 & 0 & 1 \end{bmatrix} ~;~~
  \boldsymbol{B} = \boldsymbol{F}\cdot\boldsymbol{F}^T = \begin{bmatrix} 1+\gamma^2 & \gamma & 0 \\ \gamma & 1 & 0 \\ 0 & 0 & 1 \end{bmatrix}
</math>
Therefore,
:<math>
  \boldsymbol{B}^{-1} =  \begin{bmatrix} 1 & -\gamma & 0 \\ -\gamma & 1+\gamma^2 & 0 \\ 0 & 0 & 1 \end{bmatrix}
</math>
The Cauchy stress is given by
:<math>
  \boldsymbol{\sigma} = \begin{bmatrix} -p^* +2(C_1-C_2)+2C_1\gamma^2 & 2(C_1+C_2)\gamma & 0 \\ 2(C_1+C_2)\gamma & -p^* + 2(C_1 -C_2) - 2C_2\gamma^2 & 0 \\ 0 & 0 & -p^* + 2(C_1 - C_2)
\end{bmatrix}
</math>
For consistency with linear elasticity, clearly <math>\mu = 2(C_1+C_2)</math> where <math>\mu</math> is the shear modulus.
 
==Rubber==
Elastic response of rubber-like materials are often modeled based on the Mooney—Rivlin model. The constants <math>C_1,C_2</math> are determined by the fitting predicted stress from the above equations to experimental data.  The recommended tests are uniaxial tension, equibiaxial compression, equibiaxial tension, uniaxial compression, and for shear, planar tension and planar compression.  The two parameter Mooney–Rivlin model is usually valid for strains less than 100%.
 
==Notes and references==
<references/>
 
==See also==
* [[Hyperelastic material]]
* [[Finite strain theory]]
* [[Continuum mechanics]]
* [[Strain energy density function]]
* [http://www.campoly.com/index.php/download_file/view/390/108/ Application note on experimentally determining Mooney Rivlin constants]
 
{{DEFAULTSORT:Mooney-Rivlin Solid}}
[[Category:Continuum mechanics]]
[[Category:Non-Newtonian fluids]]
[[Category:Rubber properties]]
[[Category:Solid mechanics]]

Revision as of 03:10, 13 December 2013

Template:Continuum mechanics In continuum mechanics, a Mooney–Rivlin solid[1][2] is a hyperelastic material model where the strain energy density function W is a linear combination of two invariants of the left Cauchy–Green deformation tensor 𝑩. The model was proposed by Melvin Mooney in 1940 and expressed in terms of invariants by Ronald Rivlin in 1948.

The strain energy density function for an incompressible Mooney–Rivlin material is[3][4]

W=C1(I13)+C2(I23),

where C1 and C2 are empirically determined material constants, and I1 and I2 are the first and the second invariant of the unimodular component of the left Cauchy–Green deformation tensor:[5]

I¯1=J2/3I1;I1=λ12+λ22+λ32;J=det(𝑭)I¯2=J4/3I2;I2=λ12λ22+λ22λ32+λ32λ12

where 𝑭 is the deformation gradient. For an incompressible material, J=1.

Derivation

The Mooney–Rivlin model is a special case of the generalized Rivlin model (also called polynomial hyperelastic model[6]) which has the form

W=p,q=0NCpq(I¯13)p(I¯23)q+m=1MDm(J1)2m

with C00=0 where Cpq are material constants related to the distortional response and Dm are material constants related to the volumetric response. For a compressible Mooney–Rivlin material N=1,C01=C2,C11=0,C10=C1,M=1 and we have

W=C01(I¯23)+C10(I¯13)+D1(J1)2

If C01=0 we obtain a neo-Hookean solid, a special case of a Mooney–Rivlin solid.

For consistency with linear elasticity in the limit of small strains, it is necessary that

κ=2D1;μ=2(C01+C10)

where κ is the bulk modulus and μ is the shear modulus.

Cauchy stress in terms of strain invariants and deformation tensors

The Cauchy stress in a compressible hyperelastic material with a stress free reference configuration is given by

𝝈=2J[1J2/3(WI¯1+I¯1WI¯2)𝑩1J4/3WI¯2𝑩𝑩]+[WJ23J(I¯1WI¯1+2I¯2WI¯2)]1

For a compressible Mooney–Rivlin material,

WI¯1=C1;WI¯2=C2;WJ=2D1(J1)

Therefore, the Cauchy stress in a compressible Mooney–Rivlin material is given by

𝝈=2J[1J2/3(C1+I¯1C2)𝑩1J4/3C2𝑩𝑩]+[2D1(J1)23J(C1I¯1+2C2I¯2)]1

It can be shown, after some algebra, that the pressure is given by

p:=13tr(𝝈)=WJ=2D1(J1).

The stress can then be expressed in the form

𝝈=1J[p1+2J2/3(C1+I¯1C2)𝑩2J4/3C2𝑩𝑩23(C1I¯1+2C2I¯2)1].

The above equation is often written as

𝝈=1J[p1+2(C1+I¯1C2)𝑩¯2C2𝑩¯𝑩¯23(C1I¯1+2C2I¯2)1]where𝑩¯=J2/3𝑩.

For an incompressible Mooney–Rivlin material with J=1

𝝈=2(C1+I1C2)𝑩2C2𝑩𝑩23(C1I¯1+2C2I¯2)1.

Note that if J=1 then

det(𝑩)=det(𝑭)det(𝑭T)=1

Then, from the Cayley-Hamilton theorem,

𝑩1=𝑩𝑩I1𝑩+I21

Hence, the Cauchy stress can be expressed as

𝝈=p1+2C1𝑩2C2𝑩1

where p:=23(C1I1C2I2).

Cauchy stress in terms of principal stretches

In terms of the principal stretches, the Cauchy stress differences for an incompressible hyperelastic material are given by

σ11σ33=λ1Wλ1λ3Wλ3;σ22σ33=λ2Wλ2λ3Wλ3

For an incompressible Mooney-Rivlin material,

W=C1(λ12+λ22+λ323)+C2(λ12λ22+λ22λ32+λ32λ123);λ1λ2λ3=1

Therefore,

λ1Wλ1=2C1λ12+2C2λ12(λ22+λ32);λ2Wλ2=2C1λ22+2C2λ22(λ12+λ32);λ3Wλ3=2C1λ32+2C2λ32(λ12+λ22)

Since λ1λ2λ3=1. we can write

λ1Wλ1=2C1λ12+2C2(1λ32+1λ22);λ2Wλ2=2C1λ22+2C2(1λ32+1λ12)λ3Wλ3=2C1λ32+2C2(1λ22+1λ12)

Then the expressions for the Cauchy stress differences become

σ11σ33=2C1(λ12λ32)2C2(1λ121λ32);σ22σ33=2C1(λ22λ32)2C2(1λ221λ32)

Uniaxial extension

For the case of an incompressible Mooney–Rivlin material under uniaxial elongation, λ1=λ and λ2=λ3=1/λ. Then the true stress (Cauchy stress) differences can be calculated as:

σ11σ33=2C1(λ21λ)2C2(1λ2λ)σ22σ33=0

Simple tension

Comparison of experimental results (dots) and predictions for Hooke's law(1, blue line), neo-Hookean solid(2, red line) and Mooney–Rivlin solid models(3, green line)

In the case of simple tension, σ22=σ33=0. Then we can write

σ11=(2C1+2C2λ)(λ21λ)

In alternative notation, where the Cauchy stress is written as 𝑻 and the stretch as α, we can write

T11=(2C1+2C2α)(α2α1)

and the engineering stress (force per unit reference area) for an incompressible Mooney–Rivlin material under simple tension can be calculated using T11eng=T11α2α3=T11α. Hence

T11eng=(2C1+2C2α)(αα2)

If we define

T11:=T11engαα2;β:=1α

then

T11=2C1+2C2β.

The slope of the T11 versus β line gives the value of C2 while the intercept with the T11 axis gives the value of C1. The Mooney–Rivlin solid model usually fits experimental data better than Neo-Hookean solid does, but requires an additional empirical constant.

Equibiaxial tension

In the case of equibiaxial tension, the principal stretches are λ1=λ2=λ. If, in addition, the material is incompressible then λ3=1/λ2. The Cauchy stress differences may therefore be expressed as

σ11σ33=σ22σ33=2C1(λ21λ4)2C2(1λ2λ4)

The equations for equibiaxial tension are equivalent to those governing uniaxial compression.

Pure shear

A pure shear deformation can be achieved by applying stretches of the form [7]

λ1=λ;λ2=1λ;λ3=1

The Cauchy stress differences for pure shear may therefore be expressed as

σ11σ33=2C1(λ21)2C2(1λ21);σ22σ33=2C1(1λ21)2C2(λ21)

Therefore

σ11σ22=2(C1+C2)(λ21λ2)

For a pure shear deformation

I1=λ12+λ22+λ32=λ2+1λ2+1;I2=1λ12+1λ22+1λ32=1λ2+λ2+1

Therefore I1=I2.

Simple shear

The deformation gradient for a simple shear deformation has the form[7]

𝑭=1+γ𝐞1𝐞2

where 𝐞1,𝐞2 are reference orthonormal basis vectors in the plane of deformation and the shear deformation is given by

γ=λ1λ;λ1=λ;λ2=1λ;λ3=1

In matrix form, the deformation gradient and the left Cauchy-Green deformation tensor may then be expressed as

𝑭=[1γ0010001];𝑩=𝑭𝑭T=[1+γ2γ0γ10001]

Therefore,

𝑩1=[1γ0γ1+γ20001]

The Cauchy stress is given by

𝝈=[p+2(C1C2)+2C1γ22(C1+C2)γ02(C1+C2)γp+2(C1C2)2C2γ2000p+2(C1C2)]

For consistency with linear elasticity, clearly μ=2(C1+C2) where μ is the shear modulus.

Rubber

Elastic response of rubber-like materials are often modeled based on the Mooney—Rivlin model. The constants C1,C2 are determined by the fitting predicted stress from the above equations to experimental data. The recommended tests are uniaxial tension, equibiaxial compression, equibiaxial tension, uniaxial compression, and for shear, planar tension and planar compression. The two parameter Mooney–Rivlin model is usually valid for strains less than 100%.

Notes and references

  1. Mooney, M., 1940, A theory of large elastic deformation, Journal of Applied Physics, 11(9), pp. 582-592.
  2. Rivlin, R. S., 1948, Large elastic deformations of isotropic materials. IV. Further developments of the general theory, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 241(835), pp. 379-397.
  3. Boulanger, P. and Hayes, M. A., 2001, Finite amplitude waves in Mooney–Rivlin and Hadamard materials, in Topics in Finite Elasticity, ed. M. A Hayes and G. Soccomandi, International Center for Mechanical Sciences.
  4. C. W. Macosko, 1994, Rheology: principles, measurement and applications, VCH Publishers, ISBN 1-56081-579-5.
  5. The characteristic polynomial of the linear operator corresponding to the second rank three-dimensional Finger tensor (also called the left Cauchy–Green deformation tensor) is usually written
    pB(λ)=λ3a1λ2+a2λa3
    In this article, the trace a1 is written I1, the next coefficient a2 is written I2, and the determinant a3 would be written I3.
  6. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  7. 7.0 7.1 Ogden, R. W., 1984, Nonlinear elastic deformations, Dover

See also