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| {{enzyme
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| | Name = desacetoxyvindoline 4-hydroxylase
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| | EC_number = 1.14.11.20
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| | CAS_number = 132084-83-4
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| | IUBMB_EC_number = 1/14/11/20
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| | GO_code = 0050590
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| In [[enzymology]], a '''deacetoxyvindoline 4-hydroxylase''' ({{EC number|1.14.11.20}}) is an [[enzyme]] that [[catalysis|catalyzes]] the [[chemical reaction]]
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| :deacetoxyvindoline + 2-oxoglutarate + O<sub>2</sub> <math>\rightleftharpoons</math> deacetylvindoline + succinate + CO<sub>2</sub> | |
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| The 3 [[substrate (biochemistry)|substrates]] of this enzyme are [[deacetoxyvindoline]], [[2-oxoglutarate]], and [[oxygen|O<sub>2</sub>]], whereas its 3 [[product (chemistry)|products]] are [[deacetylvindoline]], [[succinate]], and [[carbon dioxide|CO<sub>2</sub>]].
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| This enzyme belongs to the family of [[oxidoreductase]]s, specifically those acting on paired donors, with O2 as oxidant and incorporation or reduction of oxygen. The oxygen incorporated need not be derived from O2 with 2-oxoglutarate as one donor, and incorporation of one atom o oxygen into each donor. The systematic name of this enzyme class is '''deacetoxyvindoline,2-oxoglutarate:oxygen oxidoreductase (4beta-hydroxylating)'''. Other names in common use include '''desacetoxyvindoline 4-hydroxylase''', '''desacetyoxyvindoline-17-hydroxylase''', '''D17H''', '''desacetoxyvindoline,2-oxoglutarate:oxygen oxidoreductase''', and '''(4beta-hydroxylating)'''. This enzyme participates in [[indole and ipecac alkaloid biosynthesis]].
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| ==References==
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| {{reflist|1}}
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| * {{cite journal | author = Foucher AL, McIntosh A, Douce G, Wastling J, Tait A, Turner CM | date = 2006 | title = A proteomic analysis of arsenical drug resistance in Trypanosoma brucei | journal = Proteomics. | volume = 6 | pages = 2726–32 | pmid = 16526094 | doi = 10.1002/pmic.200500419 | issue = 9 }}
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| * {{cite journal | author = De Carolis E, De Luca V | date = 1993 | title = Purification, characterization, and kinetic analysis of a 2-oxoglutarate-dependent dioxygenase involved in vindoline biosynthesis from Catharanthus roseus | journal = J. Biol. Chem. | volume = 268 | pages = 5504–11 | pmid = 8449913 | issue = 8 }}
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| * {{cite journal | author = Vazquez-Flota FA, De Luca V | date = 1998 | title = Developmental and light regulation of desacetoxyvindoline 4-hydroxylase in catharanthus roseus (L.) G. Don. . Evidence Of a multilevel regulatory mechanism | journal = Plant. Physiol. | volume = 117 | pages = 1351–61 | pmid = 9701591 | doi = 10.1104/pp.117.4.1351 | issue = 4 | pmc = 34899 }}
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| {{1.14-enzyme-stub}}
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| [[Category:EC 1.14.11]]
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| [[Category:Enzymes of unknown structure]]
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