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{{refimprove|date=May 2011}}
Consider a system <ref name=DMS>http://www.dublinmathematicsschool.ie/Notes/Derivationofpartitionfunction.pdf</ref>  <math>S</math>  embedded into a [[heat bath]] <math>B</math>. The total [[Energy]] of the system <math>S</math> and <math>B</math> is <math>E</math>. Let <math>p_i</math> denote the probability that the system <math>S</math> is in [[microstate]] <math>i</math> with Energy <math>E_i</math>. The probability <math>p_i</math> will be proportional to the number of microstates in the total [[Closed system (thermodynamics)|closed system]] whereby the system <math>S</math> is in microstate <math>i</math> with Energy <math>E_i</math>. But, this will be proportional to the number of microstates of the heat bath <math>B</math> with Energy <math>E - E_i</math>.
 
<math>
\begin{align}
p_i &\propto \Omega_B\left(E_B\right) \\
&= \Omega_B \left(E - E_i\right) \\
\Rightarrow k \ln \Omega_B \left( E - E_i \right) & \approx k \ln \Omega_B \left(E\right) - \frac{\partial}{\partial E} \left(k \ln \Omega_B\left(E\right)\right) E_i \\
& \approx k \ln \Omega_B \left(E\right) - \frac{\partial S_B}{\partial E}  E_i \\
& \approx k \ln \Omega_B \left(E\right) - \frac{E_i}{T} \\
\Rightarrow k \ln p_i & \propto k \ln \Omega_B \left(E\right) - \frac{E_i}{T} \\
\Rightarrow  p_i & \propto  e^{\ln \Omega_B \left(E\right) - \frac{E_i}{kT}} \\
\Rightarrow  p_i & \propto  \Omega_B \left(E\right) e^{ - \frac{E_i}{kT}} \\
\Rightarrow  p_i & \propto  e^{- \frac{E_i}{kT}}.
\end{align}
</math>
 
We shall define <math>\beta := \frac{1}{kT}</math> and so we have the result; <math>p_i \propto e^{- \beta E_i } </math>
 
The [[partition function (statistical mechanics)|Partition Function]] is the [[Normalizing constant|normalisation constant]] that allows us to find the [[probability]].
 
<math>
\begin{align}
Z & :=  \sum_i  e^{- \beta E_i}
\end{align}
</math>
 
==References==
<References/>
 
[[Category:Partition functions]]

Latest revision as of 11:16, 4 January 2015



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