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Problem of points

2013-11-08T14:37:18Z

66.168.210.204: /* References */ Added book by Devlin.

This page provides supplementary chemical data on [[propan-1-ol|''n''-propanol]]. 

== Material Safety Data Sheet == 

The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS for '''propan-1-ol''' is available from [http://hazard.com/msds/mf/baker/baker/files/p6390.htm Mallinckrodt Baker].

== Structure and properties == 

{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]], ''n''D
| 1.383 at 25°C 
|-
| [[Abbe number]]
|? 
|-
| [[Dielectric constant]], εr
| 20.1 ε0 at 25 °C 
|-
| [[Bond strength]]
| ? 
|-
| [[Bond length]]
| ? 
|-
| [[Bond angle]]
| ? 
|-
| [[Magnetic susceptibility]]
| ? 
|-
| [[Surface tension]]
| 23.78 dyn/cm at 20°C
|-
| [[Viscosity]]<ref name="crcF31">''CRC Handbook of Chemistry and Physics'', 47th ed. p F-31 - F-42</ref>
|
{|
|-
| 3.893 mPa·s || at 0°C
|-
| 2.52 mPa·s || at 15°C
|-
| 2.256 mPa·s || at 20°C
|-
| 1.72 mPa·s || at 30°C
|-
| 1.405 mPa·s || at 40°C
|-
| 1.130 mPa·s || at 50°C
|-
| 0.760 mPa·s || at 70°C
|-
|}
|-
|}

== Thermodynamic properties == 

{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 148.75 K (–124.4 °C), ? Pa
|-
| [[Critical point (chemistry)|Critical point]]
| 536.9 K (263.8 °C), 5200 kPa
|-
| [[Standard enthalpy change of fusion|Std enthalpy change of fusion]], Δfus''H''<s>o</s>
| 5.37 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change of fusion]], Δfus''S''<s>o</s>
| 36 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change of vaporization]], Δvap''H''<s>o</s>
| 47.5 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change of vaporization]], Δvap''S''<s>o</s>
| ? J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change of formation]], Δf''H''<s>o</s>solid
| ? kJ/mol
|-
| [[Standard molar entropy]], ''S''<s>o</s>solid
| 112.7 J/(mol K)
|-
| [[Heat capacity]], ''cp''
| 106.3 J/(mol K) at –123°C
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change of formation]], Δf''H''<s>o</s>liquid
| –303.0 kJ/mol
|-
| [[Standard molar entropy]], ''S''<s>o</s>liquid
| 192.8 J/(mol K)
|-
| [[Enthalpy of combustion]], Δc''H''<s>o</s>
| –2021 kJ/mol
|-
| [[Heat capacity]], ''cp''
| 144.4 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change of formation]], Δf''H''<s>o</s>gas
| –255 kJ/mol
|-
| [[Standard molar entropy]], ''S''<s>o</s>gas
| 322.49 J/(mol K)
|-
| [[Heat capacity]], ''cp''
| 85.56 J/(mol K) at 25°
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="crcD104">''CRC Handbook of Chemistry and Physics'' 47th ed, p D-104</ref>
| a = 1512 L2 kPa/mol2 b = 0.1029 liter per mole
|-
|}

==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
|-
| {{chembox header}} | '''T in °C''' || –15.0 || 14.7 || 36.4 || 52.8 || 82.0 || 97.8 || 117.0 || 149.0 || 177.0 || 210.8 || 250.0 ||  —
|}
Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.

[[Image:logNpropanolVaporPressure.png|thumb|713px|left|'''log10 of ''n''-propanol vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 7.702226 \log_e(T+273.15) - \frac {8002.693} {T+273.15} + 71.71697 + 3.950448 \times 10^{-07} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|publisher=Chemical Engineering Research Information Center|accessdate=19 May 2007|format=Queriable database}}</ref>]]{{Clear}}

==Distillation data==
{|
|- valign="top"
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/Water'''<ref name="cheric_b">{{Cite web|url=http://www.cheric.org/research/kdb/hcvle/hcvle.php|title=Binary Vapor-Liquid Equilibrium Data|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=19 May 2007}}</ref> ''P'' = 100 kPa
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole water
|- {{chembox header}}
! liquid !! vapor
|-
| 96.60 || 0.00 || 0.00
|-
| 96.25 || 1.3 || 2.5
|-
| 94.69 || 3.8 || 9.7
|-
| 92.92 || 8.3 || 19.4
|-
| 90.64 || 16.0 || 31.7
|-
| 89.31 || 22.6 || 39.0
|-
| 88.48 || 28.3 || 43.7
|-
| 87.67 || 35.6 || 48.7
|-
| 87.32 || 42.6 || 52.2
|-
| 87.18 || 50.0 || 55.0
|-
| 87.13 || 58.3 || 57.2
|-
| 87.12 || 64.8 || 58.5
|-
| 87.17 || 70.8 || 59.5
|-
| 87.29 || 76.3 || 60.3
|-
| 87.47 || 81.7 || 60.8
|-
| 87.63 || 85.3 || 61.3
|-
| 87.78 || 88.3 || 61.9
|-
| 87.97 || 91.1 || 62.7
|-
| 88.28 || 92.6 || 63.2
|-
| 88.62 || 94.5 || 64.3
|-
| 89.26 || 95.7 || 66.3
|-
| 90.15 || 96.7 || 68.3
|-
| 91.91 || 97.8 || 73.9
|-
| 93.72 || 98.5 || 79.4
|-
| 95.56 || 99.1 || 85.4
|-
| 97.08 || 99.6 || 90.5
|-
| 98.80 || 99.9 || 98.4
|-
| 99.63 || 100.0 || 100.0
|-
|}
|    
|
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/[[Methanol]]'''<ref name="cheric_b"/> ''P'' = 760 mm Hg
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole methanol
|- {{chembox header}}
! liquid !! vapor
|-
| 92.30 || 9.2 || 23.5
|-
| 88.88 || 18.0 || 41.2
|-
| 83.90 || 28.0 || 56.2
|-
| 82.53 || 32.0 || 61.0
|-
| 80.25 || 38.0 || 67.5
|-
| 78.15 || 45.9 || 75.3
|-
| 74.46 || 58.1 || 83.2
|-
| 74.42 || 58.3 || 83.5
|-
| 71.28 || 68.0 || 88.8
|-
| 69.40 || 76.4 || 92.8
|-
| 68.30 || 82.2 || 94.0
|-
| 67.08 || 86.2 || 95.5
|-
|}
|-
|  
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/[[Butanone]]'''<ref name="cheric_b"/> ''P'' = 760 mm Hg
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole butanone
|- {{chembox header}}
! liquid !! vapor
|-
| 94.8 || 5.4 || 12.5
|-
| 93.0 || 9.3 || 20.6
|-
| 91.8 || 12.8 || 27.1
|-
| 90.3 || 17.1 || 33.7
|-
| 88.9 || 23.5 || 41.3
|-
| 87.7 || 28.4 || 46.9
|-
| 86.1 || 36.6 || 54.7
|-
| 84.9 || 44.0 || 60.5
|-
| 83.8 || 53.3 || 67.7
|-
| 83.5 || 57.2 || 70.1
|-
| 82.5 || 64.1 || 74.8
|-
| 81.6 || 73.0 || 81.0
|-
| 81.0 || 80.4 || 85.9
|-
| 80.4 || 87.9 || 90.9
|-
| 79.9 || 94.3 || 95.7
|-
|}
|}
|    
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/[[Cyclohexane]]'''<ref name="cheric_b"/> ''P'' = 101.325 kPa
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole cyclohexane
|- {{chembox header}}
! liquid !! vapor
|-
| 80.42 || 100 || 100
|-
| 77.42 || 96.46 || 88.36
|-
| 76.40 || 95.27 || 85.29
|-
| 75.71 || 93.97 || 83.35
|-
| 75.18 || 91.59 || 80.91
|-
| 74.92 || 89.52 || 79.43
|-
| 74.59 || 86.19 || 77.89
|-
| 74.40 || 80.52 || 76.29
|-
| 74.33 || 78.11 || 75.69
|-
| 74.29 || 75.91 || 75.13
|-
| 74.27 || 74.19 || 74.75
|-
| 74.28 || 71.43 || 74.30
|-
| 74.33 || 68.00 || 73.70
|-
| 74.43 || 64.26 || 72.87
|-
| 74.49 || 61.21 || 72.20
|-
| 74.77 || 54.09 || 70.71
|-
| 75.23 || 48.00 || 69.53
|-
| 75.59 || 41.10 || 67.48
|-
| 76.78 || 33.29 || 64.73
|-
| 77.72 || 28.53 || 62.71
|-
| 79.12 || 23.01 || 59.03
|-
| 81.11 || 17.35 || 53.39
|-
| 82.69 || 14.44 || 49.70
|-
| 84.90 || 10.73 || 42.87
|-
| 86.64 || 8.44 || 38.28
|-
| 89.34 || 4.75 || 28.90
|-
| 90.65 || 3.60 || 24.39
|-
| 91.88 || 2.70 || 19.94
|-
| 92.85 || 2.13 || 16.06
|-
| 93.44 || 1.64 || 13.64
|-
| 97.0 || 0.0 || 0.0
|-
|}
|    
|
{|
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/[[hexane|''n''-Hexane]]'''<ref name="cheric_b"/> ''P'' = 760 mm Hg
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole ''n''-propanol
|- {{chembox header}}
! liquid !! vapor
|-
| 77.70 || 2.3 || 13.6
|-
| 70.05 || 6.0 || 25.7
|-
| 68.25 || 11.7 || 42.4
|-
| 64.70 || 21.0 || 55.8
|-
| 64.10 || 24.6 || 60.0
|-
| 63.90 || 28.6 || 63.7
|-
| 62.25 || 39.8 || 67.2
|-
| 62.20 || 41.7 || 67.2
|-
| 61.90 || 49.3 || 69.1
|-
| 61.55 || 59.3 || 70.6
|-
| 61.60 || 65.7 || 72.0
|-
| 61.65 || 67.3 || 72.5
|-
| 61.60 || 72.8 || 72.7
|-
| 61.80 || 87.2 || 75.8
|-
| 62.50 || 92.3 || 79.9
|-
| 63.90 || 97.5 || 85.6
|-
|}
|-
|  
|-
|
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| bgcolor="#D0D0D0" align="center" colspan="3"| '''Vapor-liquid Equilibrium for ''n''-propanol/[[Acetone]]'''<ref name="cheric_b"/> ''P'' = 760 mm Hg
|- {{chembox header}}
! rowspan="2" | BP Temp. °C
! colspan="2" | % by mole acetone
|- {{chembox header}}
! liquid !! vapor
|-
| 86.55 || 10.80 || 40.31
|-
| 78.35 || 24.17 || 63.36
|-
| 72.65 || 35.55 || 74.32
|-
| 68.50 || 47.42 || 81.76
|-
|-
| 65.00 || 60.74 || 87.74
|-
| 62.85 || 71.29 || 91.51
|-
|}
|}
|}

== Spectral data == 

{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λmax]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| ? [[Centimetre|cm]]−1
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] 
|  
|-
| [[Carbon-13 NMR]] 
|  
|-
| Other NMR data 
|  
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of main fragments
|   
|-
|}

==References==
<references/>
* {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database}}

Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].

[[wikipedia:Chemical infobox|Disclaimer]] applies.
{{Use dmy dates|date=September 2010}}

{{DEFAULTSORT:Propan-1-Ol (Data Page)}}
[[Category:Chemical data pages]]

Runs created

2012-07-27T04:00:23Z

66.168.113.255: /* Accuracy */

== '単なる幸運 ==

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Schrödinger equation

2007-11-20T03:50:59Z

66.168.209.92: /* See also */

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2007-11-20T03:49:41Z

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2007-11-20T03:47:42Z

66.168.209.92: /* Solutions of the Schrödinger equation */

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