Berkelium

Template:Good article Template:Infobox berkelium Berkelium is a transuranic radioactive chemical element with the symbol Bk and atomic number 97, a member of the actinide and transuranium element series. It is named after the city of Berkeley, California, the location of the University of California Radiation Laboratory where it was discovered in December 1949. This was the fifth transuranium element discovered after neptunium, plutonium, curium and americium.

The major isotope of berkelium, berkelium-249, is synthesized in minute quantities in dedicated high-flux nuclear reactors, mainly at the Oak Ridge National Laboratory in Tennessee, USA, and at the Research Institute of Atomic Reactors in Dimitrovgrad, Russia. The production of the second-important isotope berkelium-247 involves the irradiation of the rare isotope curium-244 with high-energy alpha particles.

Just over one gram of berkelium has been produced in the United States since 1967. There is no practical application of berkelium outside of scientific research which is mostly directed at the synthesis of heavier transuranic elements and transactinides. A 22 milligram batch of berkelium-249 was prepared during a 250-day irradiation period and then purified for a further 90 days at Oak Ridge in 2009. This sample was used to synthesize the element ununseptium for the first time in 2009 at the Joint Institute for Nuclear Research, Russia, after it was bombarded with calcium-48 ions for 150 days. This was a culmination of the Russia–US collaboration on the synthesis of elements 113 to 118.

Berkelium is a soft, silvery-white, radioactive metal. The berkelium-249 isotope emits low-energy electrons and thus is relatively safe to handle. However, it decays with a half-life of 330 days to californium-249, which is a strong and hazardous emitter of alpha particles. This gradual transformation is an important consideration when studying the properties of elemental berkelium and its chemical compounds, since the formation of californium brings not only chemical contamination, but also self-radiation damage, and self-heating from the emitted alpha particles.

Characteristics

Physical

Double-hexagonal close packing with the layer sequence ABAC in the crystal structure of α-berkelium (A: green, B: blue, C: red)

Berkelium is a soft, silvery-white, radioactive actinide metal. In the periodic table, it is located to the right of the actinide curium, to the left of the actinide californium and below the lanthanide terbium with which it shares many similarities in physical and chemical properties. Its density of 14.78 g/cm³ lies between those of curium (13.52 g/cm³) and californium (15.1 g/cm³), as does its melting point of 986 °C, below that of curium (1340 °C) but higher than that of californium (900 °C). Berkelium is relatively soft and has one of the lowest bulk moduli among the actinides, at about 20 GPa (2Template:E Pa).

Berkelium(III) ions shows two sharp fluorescence peaks at 652 nanometers (red light) and 742 nanometers (deep red – near infrared) due to internal transitions at the f-electron shell. The relative intensity of these peaks depends on the excitation power and temperature of the sample. This emission can be observed, for example, after dispersing berkelium ions in a silicate glass, by melting the glass in presence of berkelium oxide or halide.

Between 70 K and room temperature, berkelium behaves as a Curie–Weiss paramagnetic material with an effective magnetic moment of 9.69 Bohr magnetons (µ_B) and a Curie temperature of 101 K. This magnetic moment is almost equal to the theoretical value of 9.72 µ_B calculated within the simple atomic L-S coupling model. Upon cooling to about 34 K, berkelium undergoes a transition to an antiferromagnetic state.Template:Sfn Enthalpy of dissolution in hydrochloric acid at standard conditions is −600 kJ/mol⁻¹, from which the standard enthalpy change of formation (Δ_fH°) of aqueous Bk³⁺ ions is obtained as −601 kJ/mol⁻¹. The standard potential Bk³⁺/Bk⁰ is −2.01 V. The ionization potential of a neutral berkelium atom is 6.23 eV.Template:Sfn

Allotropes

At ambient conditions, berkelium assumes its most stable α form which has a hexagonal symmetry, space group P6₃/mmc, lattice parameters of 341 pm and 1107 pm. The crystal has a double-hexagonal close packing structure with the layer sequence ABAC and so is isotypic (having a similar structure) with α-lanthanum and α-forms of actinides beyond curium. This crystal structure changes with pressure and temperature. When compressed at room temperature to 7 GPa, α-berkelium transforms to the beta modification, which has a face-centered cubic (fcc) symmetry and space group FmTemplate:Overlinem. This transition occurs without change in volume, but the enthalpy increases by 3.66 kJ/mol.Template:Sfn Upon further compression to 25 GPa, berkelium transforms to an orthorhombic γ-berkelium structure similar to that of α-uranium. This transition is accompanied by a 12% volume decrease and delocalization of the electrons at the 5f electron shell. No further phase transitions are observed up to 57 GPa.

Upon heating, α-berkelium transforms into another phase with an fcc lattice (but slightly different from β-berkelium), space group FmTemplate:Overlinem and the lattice constant of 500 pm; this fcc structure is equivalent to the closest packing with the sequence ABC. This phase is metastable and will gradually revert to the original α-berkelium phase at room temperature. The temperature of the phase transition is believed to be quite close to the melting point.

Chemical

Like all actinides, berkelium dissolves in various aqueous inorganic acids, liberating gaseous hydrogen and converting into the berkelium(III) state. This trivalent oxidation state (+3) is the most stable, especially in aqueous solutions, but tetravalent (+4) and possibly divalent (+2) berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed lanthanum chloride-strontium chloride melts.Template:Sfn A similar behavior is observed for the lanthanide analogue of berkelium, terbium. Aqueous solutions of Bk³⁺ ions are green in most acids. The color of Bk⁴⁺ ions is yellow in hydrochloric acid and orange-yellow in sulfuric acid.Template:SfnTemplate:SfnTemplate:Sfn Berkelium does not react rapidly with oxygen at room temperature, possibly due to the formation of a protective oxide layer surface. However, it reacts with molten metals, hydrogen, halogens, chalcogens and pnictogens to form various binary compounds.Template:Sfn

Isotopes

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church. About twenty isotopes and six nuclear isomers (excited states of an isotope) of berkelium have been characterized with the atomic numbers ranging from 235 to 254. All of them are radioactive. The longest half-lives are observed for ²⁴⁷Bk (1,380 years), ²⁴⁸Bk (9 years) and ²⁴⁹Bk (330 days); the half-lives of the other isotopes range from microseconds to several days. The isotope which is the easiest to synthesize is berkelium-249. This emits mostly soft β-particles which are inconvenient for detection. Its alpha radiation is rather weak – 1.45Template:E% with respect to the β-radiation – but is sometimes used to detect this isotope. The second important berkelium isotope, berkelium-247, is an alpha-emitter, as are most actinide isotopes.

Occurrence

All berkelium isotopes have a half-life far too short to be primordial. Therefore, all primordial berkelium, that is, berkelium present on the Earth during its formation, has decayed by now.

On Earth, berkelium is mostly concentrated in certain areas, which were used for the atmospheric nuclear weapons tests between 1945 and 1980, as well as at the sites of nuclear incidents, such as the Chernobyl disaster, Three Mile Island accident and 1968 Thule Air Base B-52 crash. Analysis of the debris at the testing site of the first U.S. hydrogen bomb, Ivy Mike, (1 November 1952, Enewetak Atoll), revealed high concentrations of various actinides, including berkelium. For reasons of military secrecy, this result was published only in 1956.

Nuclear reactors produce mostly, among the berkelium isotopes, berkelium-249. During the storage and before the fuel disposal, most of it beta decays to californium-249. The latter has a half-life of 351 years, which is relatively long when compared to the other isotopes produced in the reactor, and is therefore undesirable in the disposal products.

A few atoms of berkelium can be produced by neutron capture reactions and beta decay in very highly concentrated uranium-bearing deposits, thus making it the rarest naturally occurring element.

History

Glenn T. Seaborg

The 60-inch cyclotron at the Lawrence Radiation Laboratory, University of California, Berkeley, in August 1939

Berkelium is named after UC Berkeley

Although very small amounts of berkelium were possibly produced in previous nuclear experiments, it was first intentionally synthesized, isolated and identified in December 1949 by Glenn T. Seaborg, Albert Ghiorso and Stanley G. Thompson. They used the 60-inch cyclotron at the University of California, Berkeley. Similar to the nearly simultaneous discovery of americium (element 95) and curium (element 96) in 1944, the new elements berkelium and californium (element 98) were both produced in 1949–1950.

The name choice for element 97 followed the previous tradition of the Californian group to draw an analogy between the newly discovered actinide and the lanthanide element positioned above it in the periodic table. Previously, americium was named after a continent as its analogue europium, and curium honored scientists Marie and Pierre Curie as the lanthanide above it, gadolinium, was named after the explorer of the rare earth elements Johan Gadolin. Thus the discovery report by the Berkeley group reads: "It is suggested that element 97 be given the name berkelium (symbol Bk) after the city of Berkeley in a manner similar to that used in naming its chemical homologue terbium (atomic number 65) whose name was derived from the town of Ytterby, Sweden, where the rare earth minerals were first found." This tradition ended on berkelium, though, as the naming of the next discovered actinide, californium, was not related to its lanthanide analogue dysprosium, but after the discovery place.

The most difficult steps in the synthesis of berkelium were its separation from the final products and the production of sufficient quantities of americium for the target material. First, americium (²⁴¹Am) nitrate solution was coated on a platinum foil, the solution was evaporated and the residue converted by annealing to americium dioxide (AmO₂). This target was irradiated with 35 MeV alpha particles for 6 hours in the 60-inch cyclotron at the Lawrence Radiation Laboratory, University of California, Berkeley. The (α,2n) reaction induced by the irradiation yielded the ²⁴³Bk isotope and two free neutrons:

$\mathrm {^{241}_{\ 95}Am\ +\ _{2}^{4}He\ \longrightarrow \ _{\ 97}^{243}Bk\ +\ 2\ _{0}^{1}n}$

After the irradiation, the coating was dissolved with nitric acid and then precipitated as the hydroxide using concentrated aqueous ammonia solution. The product was centrifugated and re-dissolved in nitric acid. To separate berkelium from the unreacted americium, this solution was added to a mixture of ammonium and ammonium sulfate and heated to convert all the dissolved americium into the oxidation state +6. Unoxidized residual americium was precipitated by the addition of hydrofluoric acid as americium(III) fluoride (Template:Chem). This step yielded a mixture of the accompanying product curium and the expected element 97 in form of trifluorides. The mixture was converted to the corresponding hydroxides by treating it with potassium hydroxide, and after centrifugation, was dissolved in perchloric acid.

Chromatographic elution curves revealing the similarity between the lanthanides terbium (Tb), gadolinium (Gd), and europium (Eu) and their corresponding actinides berkelium (Bk), curium (Cm), and americium (Am)

Further separation was carried out in the presence of a citric acid/ammonium buffer solution in a weakly acidic medium (pH≈3.5), using ion exchange at elevated temperature. The chromatographic separation behavior was then unknown for the element 97, but was anticipated by analogy with terbium (see elution curves). First results were disappointing as no alpha-particle emission signature could be detected from the elution product. Only the further search for characteristic X-rays and conversion electron signals resulted in the identification of a berkelium isotope. Its mass number was uncertain between 243 and 244 in the initial report, but was later established as 243.

Synthesis and extraction

Preparation of isotopes

Berkelium is produced by bombarding lighter actinides uranium (²³⁸U) or plutonium (²³⁹Pu) with neutrons in a nuclear reactor. In a more common case of uranium fuel, plutonium is produced first by neutron capture (the so-called (n,γ) reaction or neutron fusion) followed by beta-decay:

$\mathrm {^{238}_{\ 92}U\ {\xrightarrow {(n,\gamma )}}\ _{\ 92}^{239}U\ {\xrightarrow[{23.5\ min}]{\beta ^{-}}}\ _{\ 93}^{239}Np\ {\xrightarrow[{2.3565\ d}]{\beta ^{-}}}\ _{\ 94}^{239}Pu}$ (the times are half-lives)

Plutonium-239 is further irradiated by a source that has a high neutron flux, several times higher than a conventional nuclear reactor, such as the 85-megawatt High Flux Isotope Reactor (HFIR) at the Oak Ridge National Laboratory in Tennessee, USA. The higher flux promotes fusion reactions involving not one but several neutrons, converting ²³⁹Pu to ²⁴⁴Cm and then to ²⁴⁹Cm:

$\mathrm {^{239}_{\ 94}Pu\ {\xrightarrow {4(n,\gamma )}}\ _{\ 94}^{243}Pu\ {\xrightarrow[{4.956\ h}]{\beta ^{-}}}\ _{\ 95}^{243}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{244}Am\ {\xrightarrow[{10.1\ h}]{\beta ^{-}}}\ _{\ 96}^{244}Cm} \quad ;\quad \mathrm {^{244}_{\ 96}Cm\ {\xrightarrow {5(n,\gamma )}}\ _{\ 96}^{249}Cm}$

Curium-249 has a short half-life of 64 minutes, and thus its further conversion to ²⁵⁰Cm has a low probability. Instead, it transforms by beta-decay into ²⁴⁹Bk:

$\mathrm {^{249}_{\ 96}Cm\ {\xrightarrow[{64.15\ min}]{\beta ^{-}}}\ _{\ 97}^{249}Bk\ {\xrightarrow[{330\ d}]{\beta ^{-}}}\ _{\ 98}^{249}Cf}$

The thus-produced ²⁴⁹Bk has a long half-life of 330 days and thus can capture another neutron. However, the product, ²⁵⁰Bk, again has a relatively short half-life of 3.212 hours and thus, does not yield any heavier berkelium isotopes. Instead decays to the californium isotope ²⁵⁰Cf:

$\mathrm {^{249}_{\ 97}Bk\ {\xrightarrow {(n,\gamma )}}\ _{\ 97}^{250}Bk\ {\xrightarrow[{3.212\ h}]{\beta ^{-}}}\ _{\ 98}^{250}Cf}$

Although ²⁴⁷Bk is the most stable isotope of berkelium, its production in nuclear reactors is very inefficient due to the long half-life of its potential progenitor curium-247, which does not allow it sufficient time to beta decay before capturing another neutron. Thus, ²⁴⁹Bk is the most accessible isotope of berkelium, which still, is available only in small quantities (only 0.66 grams have been produced in the US over the period 1967–1983Template:Sfn) at a high price of the order 185 USD per microgram.

The isotope ²⁴⁸Bk was first obtained in 1956 by bombarding a mixture of curium isotopes with 25 MeV α-particles. Although its direct detection was hindered by strong signal interference with ²⁴⁵Bk, the existence of a new isotope was proven by the growth of the decay product ²⁴⁸Cf which had been previously characterized. The half-life of ²⁴⁸Cf was estimated as 23 ± 5 hours and a more reliable value still is not known. Berkelium-247 was produced during the same year by irradiating ²⁴⁴Cm with alpha-particles:

$\mathrm {^{244}_{\ 96}Cm\ {\xrightarrow[{}]{(\alpha ,n)}}\ _{\ 98}^{247}Cf\ {\xrightarrow[{3.11\ h}]{\epsilon }}\ _{\ 97}^{247}Bk}$

$\mathrm {^{244}_{\ 96}Cm\ {\xrightarrow[{}]{(\alpha ,p)}}\ _{\ 97}^{247}Bk}$

Berkelium-242 was synthesized in 1979 by bombarding ²³⁵U with ¹¹B, ²³⁸U with ¹⁰B, ²³²Th with ¹⁴N or ²³²Th with ¹⁵N. It converts by electron capture to ²⁴²Cm with a half-life of 7.0 ± 1.3 minutes. A search for an initially suspected isotope ²⁴¹Bk was then unsuccessful; ²⁴¹Bk has since been synthesized.

$\mathrm {^{235}_{\ 92}U\ +\ _{\ 5}^{11}B\ \longrightarrow \ _{\ 97}^{242}Bk\ +\ 4\ _{0}^{1}n\quad ;\quad _{\ 90}^{232}Th\ +\ _{\ 7}^{14}N\ \longrightarrow \ _{\ 97}^{242}Bk\ +\ 4\ _{0}^{1}n}$

$\mathrm {^{238}_{\ 92}U\ +\ _{\ 5}^{10}B\ \longrightarrow \ _{\ 97}^{242}Bk\ +\ 6\ _{0}^{1}n\quad ;\quad _{\ 90}^{232}Th\ +\ _{\ 7}^{15}N\ \longrightarrow \ _{\ 97}^{242}Bk\ +\ 5\ _{0}^{1}n}$

Separation

The fact that berkelium readily assumes oxidation state +4 in solids, and is relatively stable in this state in liquids greatly assists separation of berkelium away from many other actinides. These are inevitably produced in relatively large amounts during the nuclear synthesis and often favor the +3 state. This fact was not yet known in the initial experiments, which used a more complex separation procedure. Various oxidation agents can be applied to the berkelium(III) solutions to convert it to the +4 state, such as bromates (Template:Chem), bismuthates (Template:Chem), chromates (Template:Chem and CrTemplate:SuOTemplate:Su), silver(I) thiolate (Template:Chem), lead(IV) oxide (Template:Chem), ozone (Template:Chem), or photochemical oxidation procedures. Berkelium(IV) is then extracted with ion exchange, extraction chromatography or liquid-liquid extraction using HDEHP (bis-(2-ethylhexyl) phosphoric scid), amines, tributyl phosphate or various other reagents. These procedures separate berkelium from most trivalent actinides and lanthanides, except for the lanthanide cerium (lanthanides are absent in the irradiation target but are created in various nuclear fission decay chains).Template:Sfn

A more detailed procedure adopted at the Oak Ridge National Laboratory was as follows: the initial mixture of actinides is processed with ion exchange using lithium chloride reagent, then precipitated as hydroxides, filtered and dissolved in nitric acid. It is then treated with high-pressure elution from cation exchange resins, and the berkelium phase is oxidized and extracted using one of the procedures described above.Template:Sfn Reduction of the thus-obtained berkelium(IV) to the +3 oxidation state yields a solution, which is nearly free from other actinides (but contains cerium). Berkelium and cerium are then separated with another round of ion-exchange treatment.Template:Sfn

Bulk metal preparation

In order to characterize chemical and physical properties of solid berkelium and its compounds, a program was initiated in 1952 at the Material Testing Reactor, Arco, Idaho, US. It resulted in preparation of an eight-gram plutonium-239 target and in the first production of macroscopic quantities (0.6 micrograms) of berkelium by Burris B. Cunningham and Stanley G. Thompson in 1958, after a continuous reactor irradiation of this target for six years.Template:Sfn This irradiation method was and still is the only way of producing weighable amounts of the element, and most solid-state studies of berkelium have been conducted on microgram or submicrogram-sized samples.Template:Sfn

The world's major irradiation sources are the 85-megawatt High Flux Isotope Reactor at the Oak Ridge National Laboratory in Tennessee, USA, and the SM-2 loop reactor at the Research Institute of Atomic Reactors (NIIAR) in Dimitrovgrad, Russia, which are both dedicated to the production of transcurium elements (atomic number greater than 96). These facilities have similar power and flux levels, and are expected to have comparable production capacities for transcurium elements, although the quantities produced at NIIAR are not publicly reported. In a "typical processing campaign" at Oak Ridge, tens of grams of curium are irradiated to produce decigram quantities of californium, milligram quantities of berkelium-249 and einsteinium, and picogram quantities of fermium.Template:Sfn In total, just over one gram of berkelium-249 has been produced at Oak Ridge since 1967.

The first berkelium metal sample weighing 1.7 micrograms was prepared in 1971 by the reduction of berkelium(III) fluoride with lithium vapor at 1000 °C; the fluoride was suspended on a tungsten wire above a tantalum crucible containing molten lithium. Later, metal samples weighting up to 0.5 milligrams were obtained with this method.Template:Sfn

$\mathrm {BkF_{3}\ +\ 3\ Li\ \longrightarrow \ Bk\ +\ 3\ LiF}$

Similar results are obtained with berkelium(IV) fluoride. Berkelium metal can also be produced by the reduction of berkelium(IV) oxide with thorium or lanthanum.Template:Sfn

Compounds

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Oxides

Two oxides of berkelium are known, with the berkelium oxidation state of +3 (Bk₂O₃) and +4 (BkO₂). Berkelium(IV) oxide is a brown solid, while berkelium(III) oxide is a yellow-green solid with a melting point of 1920 °CTemplate:Sfn and is formed from BkO₂ by reduction with molecular hydrogen:

$\mathrm {2\ BkO_{2}\ +\ H_{2}\ \longrightarrow \ Bk_{2}O_{3}\ +\ H_{2}O}$

Upon heating to 1200 °C, the oxide Bk₂O₃ undergoes a phase change; it undergoes another phase change at 1750 °C. Such three-phase behavior is typical for the actinide sesquioxides. Berkelium(II) oxide, BkO, has been reported as a brittle gray solid but its exact chemical composition remains uncertain.Template:Sfn

Halides

In halides, berkelium assumes the oxidation states +3 and +4.Template:Sfn The +3 state is the most stable, especially in solutions, while the tetravalent halides BkF₄ and Cs₂BkCl₆ are only known in the solid phase.Template:Sfn The coordination of berkelium atom in its trivalent fluoride and chloride is tricapped trigonal prismatic, with the coordination number of 9. In trivalent bromide, it is bicapped trigonal prismatic (coordination 8) or octahedral (coordination 6), and in the iodide it is octahedral.Template:Sfn

Oxidation number	F	Cl	Br	I
+3	BkF3 (yellowTemplate:Sfn)	BkCl3 (greenTemplate:Sfn) Cs2NaBkCl6Template:Sfn	BkBr3 (yellow-greenTemplate:Sfn)	BkI3 (yellowTemplate:Sfn)
+4	BkF4 (yellowTemplate:Sfn)	Cs2BkCl6 (orangeTemplate:Sfn)

Berkelium(IV) fluoride (BkF₄) is a yellow-green ionic solid and is isotypic with uranium tetrafluoride or zirconium(IV) fluoride.Template:Sfn Berkelium(III) fluoride (BkF₃) is also a yellow-green solid, but it has two crystalline structures. The most stable phase at low temperatures is isotypic with yttrium(III) fluoride, while upon heating to between 350 and 600 °C, it transforms to the structure found in lanthanum(III) fluoride.Template:Sfn

Visible amounts of berkelium(III) chloride (BkCl₃) were first isolated and characterized in 1962, and weighed only 3 billionths of a gram. It can be prepared by introducing hydrogen chloride vapors into an evacuated quartz tube containing berkelium oxide at a temperature about 500 °C. This green solid has a melting point of 600 °C,Template:Sfn and is isotypic with uranium(III) chloride. Upon heating to nearly melting point, BkCl₃ converts into an orthorhombic phase.Template:Sfn

Two forms of berkelium(III) bromide are known: one with berkelium having coordination 6, and one with coordination 8.Template:Sfn The latter is less stable and transforms to the former phase upon heating to about 350 °C. An important phenomenon for radioactive solids has been studied on these two crystal forms: the structure of fresh and aged ²⁴⁹BkBr₃ samples was probed by X-ray diffraction over a period longer than 3 years, so that various fractions of berkelium-249 had beta decayed to californium-249. No change in structure was observed upon the ²⁴⁹BkBr₃—²⁴⁹CfBr₃ transformation. However, other differences were noted for ²⁴⁹BkBr₃ and ²⁴⁹CfBr₃. For example, the latter could be reduced with hydrogen to ²⁴⁹CfBr₂, but the former could not – this result was reproduced on individual ²⁴⁹BkBr₃ and ²⁴⁹CfBr₃ samples, as well on the samples containing both bromides. The intergrowth of californium in berkelium occurs at a rate of 0.22% per day and is an intrinsic obstacle in studying berkelium properties. Beside a chemical contamination, ²⁴⁹Cf, being an alpha emitter, brings undesirable self-damage of the crystal lattice and the resulting self-heating. The chemical effect however can be avoided by performing measurements as a function of time and extrapolating the obtained results.Template:Sfn

Other inorganic compounds

The pnictides of berkelium-249 of the type BkX are known for the elements nitrogen, phosphorus, arsenic and antimony. They crystallize in the rock-salt structure and are prepared by the reaction of either berkelium(III) hydride (BkH₃) or metallic berkelium with these elements at elevated temperature (about 600 °C) under high vacuum.

Berkelium(III) sulfide, Bk₂S₃, is prepared by either treating berkelium oxide with a mixture of hydrogen sulfide and carbon disulfide vapors at 1130 °C, or by directly reacting metallic berkelium with elemental sulfur. These procedures yield brownish-black crystals.Template:Sfn

Berkelium(III) and berkelium(IV) hydroxides are both stable in 1 molar solutions of sodium hydroxide. Berkelium(III) phosphate (BkPO₄) has been prepared as a solid, which shows strong fluorescence under excitation with a green light.Template:Sfn Berkelium hydrides are produced by reacting metal with hydrogen gas at temperatures about 250 °C. They are non-stoichiometric with the nominal formula BkH_2+x (0 < x < 1).Template:Sfn Several other salts of berkelium are known, including an oxysulfide (Bk₂O₂S), and hydrated nitrate (Template:Chem), chloride (Template:Chem), sulfate (Template:Chem) and oxalate (Template:Chem).Template:Sfn Thermal decomposition at about 600 °C in an argon atmosphere (to avoid oxidation to Template:Chem) of Template:Chem yields the crystals of berkelium(III) oxysulfate (Template:Chem). This compound is thermally stable to at least 1000 °C in inert atmosphere.Template:Sfn

Organoberkelium compounds

Berkelium forms a trigonal (η⁵–C₅H₅)₃Bk metallocene complex with three cyclopentadienyl rings, which can be synthesized by reacting berkelium(III) chloride with the molten beryllocene (Be(C₅H₅)₂) at about 70 °C. It has an amber color and a density of 2.47 g/cm³. The complex is stable to heating to at least 250 °C, and sublimates without melting at about 350 °C. The high radioactivity of berkelium gradually destroys the compound (within a period of weeks). One cyclopentadienyl ring in (η⁵–C₅H₅)₃Bk can be substituted by chlorine to yield [Bk(C₅H₅)₂Cl]₂. The optical absorption spectra of this compound are very similar to those of (η⁵–C₅H₅)₃Bk.Template:SfnTemplate:Sfn

Applications

The berkelium target used for the synthesis of ununseptium (in dissolved state)

There is currently no use for any isotope of berkelium outside of basic scientific research. Berkelium-249 is a common target nuclide to prepare still heavier transuranic elements and transactinides, such as lawrencium, rutherfordium and bohrium. It is also useful as a source of the isotope californium-249, which is used for studies on the chemistry of californium in preference to the more radioactive californium-252 that is produced in neutron bombardment facilities such as the HFIR.

A 22 milligram batch of berkelium-249 was prepared in a 250-day irradiation and then purified for 90 days at Oak Ridge in 2009. This target yielded the first 6 atoms of ununseptium at the Joint Institute for Nuclear Research (JINR), Dubna, Russia, after bombarding it with calcium ions in the U400 cyclotron for 150 days. This synthesis was a culmination of the Russia—US collaboration between JINR and Lawrence Livermore National Laboratory on the synthesis of elements 113 to 118 which was initiated in 1989.

Nuclear fuel cycle

The nuclear fission properties of berkelium are different from those of the neighboring actinides curium and californium, and they suggest berkelium to perform poorly as a fuel in a nuclear reactor. Specifically, berkelium-249 has a moderately large neutron capture cross section of 710 barns for thermal neutrons, 1200 barns resonance integral, but very low fission cross section for thermal neutrons. In a thermal reactor, much of it will therefore be converted to berkelium-250 which quickly decays to californium-250. In principle, berkelium-249 can sustain a nuclear chain reaction in a fast breeder reactor. Its critical mass is relatively high at 192 kg; it can be reduced with a water or steel reflector but would still exceed the world production of this isotope.

Berkelium-247 can maintain chain reaction both in a thermal-neutron and in a fast-neutron reactor, however, its production is rather complex and thus the availability is much lower than its critical mass, which is about 75.7 kg for a bare sphere, 41.2 kg with a water reflector and 35.2 kg with a steel reflector (30 cm thickness).

Health issues

Little is known about the effects of berkelium on human body, and analogies with other elements may not be drawn because of different radiation products (electrons for berkelium and alpha particles, neutrons, or both for most other actinides). The low energy of electrons emitted from berkelium-249 (less than 126 keV) hinders its detection, due to signal interference with other decay processes, but also makes this isotope relatively harmless to humans as compared to other actinides. However, berkelium-249 transforms with a half-life of only 330 days to the strong alpha-emitter californium-249, which is rather dangerous and has to be handled in a glove box in a dedicated laboratory.

Most available berkelium toxicity data originate from research on animals. Upon ingestion by rats, only about 0.01% berkelium ends in the blood stream. From there, about 65% goes to the bones, where it remains for about 50 years, 25% to the lungs (biological half-life about 20 years), 0.035% to the testicles or 0.01% to the ovaries where berkelium stays indefinitely. The balance of about 10% is excreted. In all these organs berkelium might promote cancer, and in the skeletal system its radiation can damage red blood cells. The maximum permissible amount of berkelium-249 in the human skeleton is 0.4 nanograms.

References

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Bibliography

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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
  My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
  My blog: http://www.primaboinca.com/view_profile.php?userid=5889534

External links

• Berkelium at The Periodic Table of Videos (University of Nottingham)

Most brokers paid and post their listings at these online property categorised portals but fail to realise that there is simply extra to it. They fail to leverage on one of the vital well-liked on-line advertising and marketing tool of their marketing campaign and that is through the social media.

In case you are among the many few who've passed the grueling Actual Estate Salesperson (RES) course, congratulations. So what next? Which agency should you be a part of? Earlier than taking the plunge, you will need to choose the proper mentor who can educate you the ropes in actual estate. An excellent mentor will allow you to navigate the complex world of real property by instructing you the way to get listings, advertising and marketing methods, real estate contracts and methods to closing your deal. He will even caution you on errors to keep away from that would land you in trouble. This has been reflected within the Industrial Production reading index for prescribed drugs. In June, the reading fell to one hundred thirty from 287. Effectively if you do not, you then're simply leaving your actual property enterprise to chance. Commons for rent

Thanks to hirepropertyagent.com.sg, i've discovered myself a good agent. He did a great job promoting my property and it was bought at an excellent value." JLL appointed unique agent for the sale of 2, 4 and 6 Dunlop Street by Expression of Curiosity. Uncommon Industrial Growth inside Pandan Meals Zone space up for sale conserving you updated with the property market 3. Work @ Residence IT Solutions As property costs cool in Hong Kong and Singapore, which have lengthy been magnets for Chinese language funding, extra money is flowing to actual property markets comparable to New York, London and Sydney. Chinese language have overtaken Russians house for sale in singapore the primary time as the biggest buyers of flats in Manhattan, in response to actual estate brokers. Condominium For Lease – Tribeca by the Waterfront (D09)

Property developer and residential landlord for flats and homes for lease and sale. Most property firms share the same database of property listings in Singapore. Due to this fact it is best to solely use only ONE agent at a time. In case you approach many agents at the similar time, very likely that they'll present you the same property. A lot confusion and embarrassment will arise should you engage many brokers. One of the best, and most of the time only, strategy to discover a good property agent in Singapore is phrase-of-mouth. Ask your friends and colleagues for reference. It is very simple to provide you with a couple of candidates since a lot of the expatriates dwelling in Singapore for a long time can have several good agent contacts to guide you. Toa Payoh, Singapore Singapore 319378 Estate

This is precisely what happened to me and my husband at the moment, to not point out a very unscrupulous developer operating in a really unprofessional manner. I need to share this story with everyone here, and please pass the message round particularly among expats communities, beware while you want to purchase property developed by VicLand Pte Ltd and if developer's agent is ECG property. There was only one unit left on the market by developer, 03-09, a 3 bed room flat. On the time my husband was out of town, and initially I liked what I saw so I instructed the developer's agent and my agent we should come back with my husband in two weeks to view it once more and make a decision after ward. Complaint / Suggestions about lousy property agent Darren Ng from Dennis Wee

This bought me thinking and I started to surprise – how much does a property agent really earn? We often hear or read about sure brokers making million dollar commissions, however is that the exception or the norm? That piqued my curiosity. Like any job, those who put in time and effort will do well and rise to the top. The ethics of exhausting work apply to the true property market as nicely. For individuals who are pondering of making a career change to develop into a property agent, you should be ready to invest the trouble to do properly. Otherwise you may just add to the statistic of brokers who eventually drop out of the realtor game. Properties that do not fall within the definition of residential properties stated above are non-residential properties Web site - www.riaschool.com.sg

Ought to you are on the lookout for new properties for investment or for own stay, we offer property recommendation and search services tailored to your needs. We have represented many together with worldwide and local buyers in efficiently finishing their property purchases. We work with main builders to bring you the latest and one of the best prime properties in Singapore. We are a one-cease service that may full your property cycle from purchase to sale. Property agents for Singapore Land Authority protecting among the government colonial properties for rent. Property leases for expatriates and foreigners. Also helps expats to purchase and promote their properties as well as property investment opportunities in Singapore and China. The Restaurant Affiliation of Singapore Template:Wikipedia books 50 year old Petroleum Engineer Kull from Dawson Creek, spends time with interests such as house brewing, property developers in singapore condo launch and camping. Discovers the beauty in planing a trip to places around the entire world, recently only coming back from . Template:Compact periodic table Template:Chemical elements named after places

30 year-old Entertainer or Range Artist Wesley from Drumheller, really loves vehicle, property developers properties for sale in singapore singapore and horse racing. Finds inspiration by traveling to Works of Antoni Gaudí.

Template:Link GA Real Estate Agent Renaldo Lester from Saint-Jean-Chrysostome, has several hobbies which include leathercrafting, property developers in singapore apartment for sale, this contact form, and crochet. Loves to see new cities and places like Ruins of Loropéni. Template:Link GA