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The Davidson correction is a simple correction that is often applied in calculations using the method of configuration interaction, which is one of several post-Hartree–Fock ab initio quantum chemistry methods in the field of computational chemistry. It was introduced by Ernest R. Davidson.

It allows one to estimate the value of the full configuration interaction energy from a limited configuration interaction expansion result, although more precisely it estimates the energy of configuration interaction up to quadruple excitations (CISDTQ) from the energy of configuration interaction up to double excitations (CISD). It uses the formula

$\mathrm{\Delta }{E}_Q=(1-a_0^2)(E_{\mathrm{C}\mathrm{I}\mathrm{S}\mathrm{D}}-E_{\mathrm{H}\mathrm{F}}),$

$E_{\mathrm{C}\mathrm{I}\mathrm{S}\mathrm{D}\mathrm{T}\mathrm{Q}}\approx E_{\mathrm{C}\mathrm{I}\mathrm{S}\mathrm{D}}+\mathrm{\Delta }{E}_Q,$

where a₀ is the coefficient of the Hartree–Fock wavefunction in the CISD expansion, E_CISD and E_HF are the energies of the CISD and Hartree–Fock wavefunctions respectively, and ΔE_Q is the correction to estimate E_CISDTQ, the energy of the CISDTQ wavefunction. Such estimation is based on perturbation theory analysis. Therefore, CISD calculation with Davidson correction included is frequently referred to as CISD(Q).

Application

Davidson correction is very popular due to its low computational cost. The correction improves contribution of electron correlation to the energy. The size-consistency and size-extensivity problems of truncated CI are alleviated but still exist. In small molecules, accuracy of the corrected energies can be similar to results from coupled cluster theory calculations.

Davidson correction does not give information about wave function. Therefore it cannot be used to correct wave-function-dependent quantities such as dipole moment, charge density and vibronic couplings. Analytical gradients for Davidson corrections are in general not available in quantum chemistry programs.

As with other perturbative approaches, Davidson correction is not reliable when the electronic structure of CISD and the reference Hartree-Fock wave functions are significantly different. The correction is invalid, when $a_0^2$ is not close to 1. This happens when multi-reference character is significant or when CISD is used to calculate a state that is not the reference state, for example, an excited state or a state with different spin multiplicity.

Size-consistency and size-extensivity problem

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church. Davidson correction improves both size consistency and size extensivity of CISD energies. Therefore, Davidson correction is frequently referred to in literature as size-consistency correction or size-extensivity correction.

However, neither Davidson correction itself nor the corrected energies are size-consistent or size-extensive. This is especially the case in larger molecules, where contribution from higher than quadruple excitations becomes more significant.

Corrections for Multi-reference CISD

Similar corrections exist for MR-CISD energies, including multi-reference Davidson correction, Pople correction, and others. These methods can be used to correct excited state energies.

See also

• Configuration interaction
• Electron correlation
• Size consistency
• Size extensivity

References

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