Isotropic manifold: Difference between revisions

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The '''Bjerrum length''' (after Danish chemist [[Niels Bjerrum]] 1879–1958
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<ref>http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=TF959550X001&JournalCode=TF</ref>)
is the separation at which the [[electrostatic]] interaction between two
[[elementary charge]]s is comparable in magnitude to the thermal energy scale,
<math>k_B T</math>, where <math>k_B</math> is the [[Boltzmann constant]] and <math>T</math> is the
[[absolute temperature]] in [[Kelvin]]. This length scale arises naturally in discussions of electrostatic,
electrodynamic and electrokinetic phenomena in [[electrolyte]]s, [[polyelectrolyte]]s and [[DLVO theory|colloidal dispersions]].
<ref>{{cite book | last1=Russel | first1=William B. | first2=D. A. | last2=Saville | first3=William R. | last3=Schowalter |
title=Colloidal Dispersions | publisher=Cambridge University Press | location=New York | year=1989}}</ref>
 
In [[SI units|standard units]], the Bjerrum length is given by
 
<math>\lambda_B = \frac{e^2}{4\pi \varepsilon_0 \varepsilon_r \  k_B T},</math>
 
where <math>e</math> is the [[elementary charge]], <math>\varepsilon_r</math> is the relative [[dielectric constant]] of the medium
and <math>\varepsilon_0</math> is the [[vacuum permittivity]].
For water at
room temperature (<math>T = 300 \mbox{ K}</math>), <math>\varepsilon_r \approx 80</math>, so that
<math>\lambda_B \approx 0.7 \mbox{nm}</math>.
 
In [[Gaussian units]], <math>4\pi\varepsilon_0 = 1</math> and the Bjerrum length has the simpler form
 
<math>\lambda_B = \frac{e^2}{\varepsilon_r k_B T}.</math>
 
==References==
{{Reflist}}
 
[[Category:Physical chemistry]]

Latest revision as of 06:44, 7 June 2014

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