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{{Other uses|Valence (disambiguation)}}
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{{Redirect|Multivalent||Polyvalence (disambiguation)}}
{{Expert-subject|chemistry|date=August 2011}}


In [[chemistry]], '''valence''', also known as '''valency''' or '''valence number''', is the number of [[Valence bond theory|valence bonds]]<ref>Note: A [[Valence bond theory|valence bond]] (or bonding equivalent) is a covalent or ionic bond, formed by the interaction of two bonding electrons.</ref>
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a given atom has formed, or can form, with one or more other atoms. For most elements the number of bonds can vary. The [[International Union of Pure and Applied Chemistry|IUPAC]] definition limits valence to ''the maximum number of univalent atoms that may combine with the atom'', that is the maximum number of valence bonds that is possible for the given element.<ref name=goldbook_valence>[[IUPAC Gold Book]] definition: [http://goldbook.iupac.org/V06588.html valence]</ref>
 
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The valence of an element depends on the number of [[valence electron]]s that may be involved in the forming of valence bonds. A '''univalent''' (monovalent) atom, ion or group has a '''valence of one''' and thus can form one [[covalent bond]]. A [[divalent]] ''[[molecular entity]]'' has a valence of two and can form two sigma bonds to two different atoms or one [[sigma bond]] plus one [[pi bond]] to a single atom.<ref name=freedictionary>The Free Dictionary: [http://medical-dictionary.thefreedictionary.com/Valence ''valence'']</ref>
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[[Alkyl group]]s and [[hydroxyl]] ions are univalent examples; [[oxo ligand]]s are divalent.


Over the last century, the concept of valence evolved into a range of approaches for describing the chemical bond, including [[Lewis structure]]s (1916), [[valence bond theory]] (1927), [[molecular orbital]]s (1928), [[VSEPR theory|valence shell electron pair repulsion theory]] (1958) and all the advanced methods of [[quantum chemistry]].
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{|
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|-
| [[File:Cyclohexanonoxime.svg|60px]] || In cyclohexanon[[oxime]] (image left), the [[nitrogen]] atom has three valence bonds and therefore a valence of three.
|}


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The [[etymology]] of the word  "valence" traces back to 1425, meaning "extract, preparation," from Latin ''valentia'' "strength, capacity," and the chemical meaning referring to the "combining power of an element" is recorded from 1884, from German ''Valenz''.<ref>[http://www.etymonline.com/index.php?search=valence&searchmode=none Valence] - Online Etymology Dictionary.</ref>
 
[[Image:Higgins-particles.jpg|350px|thumb|[[William Higgins (chemist)|William Higgins]]' combinations of ultimate particles (1789)]]
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In 1789, [[William Higgins (chemist)|William Higgins]] published views on what he called combinations of "ultimate" particles, which foreshadowed the concept of [[valency bonds]].<ref name="Partington" >{{Cite book | last = Partington | first = J.R. | title = A Short History of Chemistry | publisher = Dover Publications, Inc | year = 1989 | isbn = 0-486-65977-1}}</ref> If, for example, according to Higgins, the force between the ultimate particle of oxygen and the ultimate particle of nitrogen were 6, then the strength of the force would be divided accordingly, and likewise for the other combinations of ultimate particles (see illustration).
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The exact inception, however, of the theory of chemical valencies can be traced to an 1852 paper by [[Edward Frankland]], in which he combined the older theories of [[free radical]]s and “type theory” with thoughts on [[chemical affinity]] to show that certain elements have the tendency to combine with other elements to form compounds containing 3, i.e. in the three atom groups (e.g., ''NO<sub>3</sub>, NH<sub>3</sub>, NI<sub>3</sub>,'' etc.) or 5, i.e. in the five atom groups (e.g., ''NO<sub>5</sub>, NH<sub>4</sub>O, PO<sub>5</sub>,'' etc.), equivalents of the attached elements.  It is in this manner, according to Frankland, that their affinities are best satisfied.  Following these examples and postulates, Frankland declares how obvious it is that:<ref>Frankland, E. (1852). Phil. Trans., vol. cxlii, 417.</ref>
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{{Cquote|A tendency or law prevails (here), and that, no matter what the characters of the uniting atoms may be, the '''combining power''' of the attracting element, if I may be allowed the term, is always satisfied by the same number of these atoms.}}
== Nike Air Force 1  inspired by Roach's second to last chapter ==


This “combining power” was afterwards called '''quantivalence''' or valency (and valence by American chemists).<ref name="Partington" />
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===Covalence===
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The concept of covalence was developed in the middle of the nineteenth century in an attempt to rationalize the [[chemical formula|formulae]] of different [[chemical compound]]s. In 1919, [[Irving Langmuir]], borrowed the term to explain [[Gilbert N. Lewis]]'s [[cubical atom]] model by stating that "the number of pairs of [[electron]]s which any given atom shares with the adjacent atoms is called the ''covalence'' of that atom."  The prefix ''co-'' means "together", so that a co-valent bond means that the atoms share valence. '''Hence, if an atom, for example, had a +1 valence, meaning it has one valence electron beyond the complete shell, and another a −1 valence, meaning it requires one electron to complete its outer shell (missing an electron) ''', then a bond between these two atoms would result because they would be complementing or sharing their out of balance valence tendencies. Subsequent to this, it is now more common to speak of [[covalent bond]]s rather than "valence", which has fallen out of use in higher level work with the advances in the theory of chemical bonding, but is still widely used in elementary studies where it provides a heuristic introduction to the subject.
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== Common valences ==
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For elements in the [[Group (periodic table)|main groups]] of the [[periodic table]], the valence can vary between one and seven, but usually these elements form a number of valence bonds between one and four. The number of bonds formed by a given element was originally thought to be a fixed chemical property. In fact, in most cases this is not true. For example, [[phosphorus]] often has a valence of three, but can also have other valences.
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Nevertheless, many elements have a common valence related to their position in the periodic table, following the [[octet rule]]. Elements in the main groups '''[[Alkali metal|1]]''' (alkali metals) and '''[[Group 17|17]]''' (halogens) commonly have a valence of 1; elements in [[Alkaline earth metal|groups '''2''']] (alkaline earth metals) and '''[[Chalcogen|16]]''' (chalcogens) valence 2; elements in [[Boron group|groups '''13''']] (boron group) and '''[[Nitrogen group|15]]''' (nitrogen group) valence 3; elements in [[Carbon group|group '''14''']] (carbon group) valence 4.
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''Polyvalence'' or ''multivalence'' refers to [[Chemical species|species]] that are not restricted to a distinct number of valence [[Chemical bond|bonds]]. (Species with only one valence are univalent (monovalent)). For example, the Cs<sup>+</sup> [[cation]] is a univalent or monovalent cation, whereas the Ca<sup>2+</sup> cation is a divalent or polyvalent or multivalent cation and the Fe<sup>3+</sup> cation is a trivalent or polyvalent or multivalent cation. As a result, examples of polyvalent cations include the Ca<sup>2+</sup> cation and the Fe<sup>3+</sup> cation.{{Citation needed|date=December 2012}}
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== Valence versus oxidation state ==
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Because of the ambiguity of the term valence,<ref name=freedictionary/> nowadays other notations are used in practice. Beside the system of [[oxidation number]]s as used in ''[[Stock nomenclature]]'' for [[coordination compound]]s,<ref>[[IUPAC]], [[Gold Book]] definition: [http://goldbook.iupac.org/O04363.html ''oxidation number'']</ref> and the lambda notation, as used in the [[IUPAC nomenclature of inorganic chemistry]],<ref>[[IUPAC]], [[Gold Book]] definition: [http://goldbook.iupac.org/L03418.html ''lambda'']</ref> "[[oxidation state]]" is a more clear indication of the electronic state of atoms in a molecule.
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The "[[oxidation]] state" of an atom in a molecule gives the number of valence electrons it has gained or lost.<ref>[[IUPAC Gold Book]] definition: [http://goldbook.iupac.org/O04365.html oxidation state]</ref>
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In contrast to the ''valency number'', the ''oxidation state'' can be positive (for an electropositive atom) or negative (for an [[Electronegativity|electronegative]] atom).


Elements in a high oxidation state can have a valence larger than four. For example, in [[perchlorate]]s, chlorine has seven valence bonds and [[ruthenium]], in the +8 oxidation state in [[ruthenium tetroxide]], has even eight valence bonds.
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=="Maximum number of bonds"  definition==
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The [[International Union of Pure and Applied Chemistry]] (IUPAC) has made several attempts to arrive at an unambiguous definition of valence. The current version, adopted in 1994,:<ref>''Pure Appl. Chem.'' '''66''': 1175 (1994).</ref>
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:''The maximum number of univalent atoms (originally hydrogen or chlorine atoms) that may combine with an atom of the element under consideration, or with a fragment, or for which an atom of this element can be substituted.''<ref name=goldbook_valence/>
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[[Hydrogen]] and [[chlorine]] were originally used as examples of univalent atoms, because of their nature to form only one single bond. Hydrogen has only one ''valence electron'' and can form only one bond with an atom that has an incomplete [[Electron shell|outer shell]]. Chlorine has seven ''valence electrons'' and can form only one bond with an atom that donates a ''valence electron'' to complete chlorine's outer shell. However, chlorine can also have oxidation states from +1 to +7 and can form more than one bond by donating ''valence electrons''.
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Although hydrogen has only one valence electron, it can form bonds with more than one atom in [[Hypervalent molecule|hypervalent bonds]]. In the [[bifluoride]] ion ({{Chem|[HF|2|]|-}}), for example, it forms a [[three-center four-electron bond]] with two fluoride atoms: <math>[\ F \frac{\quad}{\quad} H\ {}^-\!F \quad \longleftrightarrow \quad F^- \ {}\!H \frac{\quad}{\quad} F\ ]</math>
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Another example is the [[Three-center two-electron bond]] in [[diborane]] (B<sub>2</sub>H<sub>6</sub>).
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(valencies according to the ''number of valence bonds'' definition and conform oxidation states)
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{| class="wikitable"
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|-
! COMPOUND !! FORMULA !! VALENCE !! OXIDATION STATE
|-
| [[Hydrogen chloride]] || HCl || H=1 &nbsp; Cl=1 || H=+1 &nbsp; Cl=−1
|-
| [[Perchloric acid]] *|| HClO<sub>4</sub> || H=1 &nbsp; Cl=7 &nbsp; O=2 || H=+1 &nbsp; Cl=+7 &nbsp; O=−2
|-
| [[Sodium hydride]] || NaH || Na=1 &nbsp; H=1 || Na=+1 &nbsp; H=−1
|-
| [[Ferrous oxide]] ** || FeO || Fe=2 &nbsp; O=2 || Fe=+2 &nbsp; O=−2
|-
| [[Ferric oxide]] ** || Fe<sub>2</sub>O<sub>3</sub> || Fe=3 &nbsp; O=2  || Fe=+3 &nbsp; O=−2
|}


<nowiki>*</nowiki> The univalent perchlorate ion (ClO<sub>4</sub><sup></sup>) has valence 1.<br />
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<nowiki>**</nowiki> Iron oxide appears in a [[crystal structure]], so no typical molecule can be identified. <br />
 
&nbsp;&nbsp;In ferrous oxide, Fe has oxidation number II, in ferric oxide, oxidation number III.
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Examples where valences and oxidation states differ due to bonds between identical atoms
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Maximum valences for the elements are based on the data from [[list of oxidation states of the elements]].
 
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