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The '''Hamaker constant''' A can be defined for a Van der Waals (VdW) body-body interaction:
:<math>A=\pi^2\times C \times \rho_1 \times \rho_2</math>
where <math>\rho_1</math> and <math>\rho_2</math> are the number of [[atom]]s per unit volume in two interacting bodies and C is the coefficient in the particle-particle pair interaction.<ref>Seung-woo Lee and Wolfgang M. Sigmund."AFM study of repulsive Van der Waals forces between Teflon AF thin film and silica or alumina." Colloids and Surfaces A: Physicochemical and Engineering Aspects. Volume 204, Issues 1-3, 23 May 2002, Pages 43&ndash;50</ref>
 
The Hamaker constant  provides the means to determine the interaction parameter C from the Van der Waals pair potential, <math>w(r)=-C/r^6</math>.
 
Hamaker's method and the associated Hamaker constant ignores the influence of an intervening medium between the two particles of interaction. In the 1950s [[E. M. Lifshitz|Lifshitz]] developed a description of the VdW energy but with consideration of the dielectric properties of this intervening medium (often a continuous phase).
 
The [[Van der Waals forces]] are effective only up to several hundred angstroms. When the interactions are too far apart the dispersion potential decays faster than <math>1/r^6</math>; this is called the [[Retarded potential|retarded]] regime and the result is a [[Casimir–Polder force]].
 
==See also==
*[[Hamaker theory]]
*[[Van der Waals Forces]]
*[[Intermolecular forces]]
 
==References==
{{Reflist}}
 
{{BranchesofChemistry}}
 
{{DEFAULTSORT:Hamaker Constant}}
[[Category:Physical chemistry]]
[[Category:Intermolecular forces]]
 
 
{{Chemistry-stub}}
{{Condensed-matter-stub}}

Revision as of 06:23, 21 February 2013

30 year-old Entertainer or Range Artist Wesley from Drumheller, really loves vehicle, property developers properties for sale in singapore singapore and horse racing. Finds inspiration by traveling to Works of Antoni Gaudí. The Hamaker constant A can be defined for a Van der Waals (VdW) body-body interaction:

A=π2×C×ρ1×ρ2

where ρ1 and ρ2 are the number of atoms per unit volume in two interacting bodies and C is the coefficient in the particle-particle pair interaction.[1]

The Hamaker constant provides the means to determine the interaction parameter C from the Van der Waals pair potential, w(r)=−C/r6.

Hamaker's method and the associated Hamaker constant ignores the influence of an intervening medium between the two particles of interaction. In the 1950s Lifshitz developed a description of the VdW energy but with consideration of the dielectric properties of this intervening medium (often a continuous phase).

The Van der Waals forces are effective only up to several hundred angstroms. When the interactions are too far apart the dispersion potential decays faster than 1/r6; this is called the retarded regime and the result is a Casimir–Polder force.

See also

References

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Template:BranchesofChemistry


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  1. ↑ Seung-woo Lee and Wolfgang M. Sigmund."AFM study of repulsive Van der Waals forces between Teflon AF thin film and silica or alumina." Colloids and Surfaces A: Physicochemical and Engineering Aspects. Volume 204, Issues 1-3, 23 May 2002, Pages 43–50
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