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{{distinguish|Fermi's interaction}} | |||
The '''Fermi contact interaction''' is the [[magnetism|magnetic]] interaction between an [[electron]] and an [[atomic nucleus]] when the electron is inside that nucleus. | |||
The parameter is usually described with the symbol A and the units are usually megahertz. The magnitude of A is given by this relationship: | |||
:<math> A = - \frac{8}{3} \pi \left \langle \boldsymbol{\mu}_n \cdot \boldsymbol{\mu}_e \right \rangle |\Psi (0)|^2\qquad \mbox{(c.g.i)}</math> | |||
and | |||
:<math> A = - \frac{2}{3} \mu_0 \left \langle \boldsymbol{\mu}_n \cdot \boldsymbol{\mu}_e \right \rangle |\Psi(0)|^2 \qquad \mbox{(S.I.)}</math> | |||
where A is the energy of the interaction, ''μ''<sub>n</sub> is the [[nuclear magnetic moment]], ''μ''<sub>e</sub> is the [[electron magnetic dipole moment]], and Ψ(0) is the electron [[wavefunction]] at the nucleus.<ref> | |||
{{cite journal | |||
|last=Bucher |first=M. | |||
|year=2000 | |||
|title=The electron inside the nucleus: An almost classical derivation of the isotropic hyperfine interaction | |||
|journal=[[European Journal of Physics]] | |||
|volume=21 |issue=1 |page=19 | |||
|arxiv= | |||
|bibcode=2000EJPh...21...19B | |||
|doi=10.1088/0143-0807/21/1/303 | |||
}}</ref> | |||
It has been pointed out that it is an ill-defined problem because the standard formulation assumes that the nucleus has a magnetic dipolar moment, which is not always the case.<ref> | |||
{{cite journal | |||
|last=Soliverez |first=C. E. | |||
|year=1980 | |||
|title=The contact hyperfine interaction: An ill-defined problem | |||
|journal=[[Journal of Physics C]] | |||
|volume=13 |issue=34 |page=L1017 | |||
|arxiv= | |||
|bibcode=1980JPhC...13.1017S | |||
|doi=10.1088/0022-3719/13/34/002 | |||
}}</ref> | |||
==Use in magnetic resonance spectroscopy== | |||
Within an [[atom]], only [[atomic orbital|s-orbitals]] have non-zero electron density at the nucleus, so the contact interaction only occurs for s-electrons. Its major manifestation is in [[electron paramagnetic resonance]] and [[nuclear magnetic resonance]] spectroscopies, where it is responsible for the appearance of isotropic [[electron paramagnetic resonance#Hyperfine coupling|hyperfine coupling]]. Roughly, the magnitude of A indicates the extent to which the unpaired spin resides on the atom. Thus, knowledge of the A values allows one to map the singly occupied [[molecular orbital]].<ref> | |||
{{cite book | |||
|last=Drago |first=R. S. | |||
|year=1992 | |||
|title=Physical Methods for Chemists | |||
|edition=2nd | |||
|publisher=[[Saunders College Publishing]] | |||
|pages= | |||
|isbn=978-0030751769 | |||
}}</ref> | |||
==History== | |||
The interaction was first derived by [[Enrico Fermi]] in 1930.<ref> | |||
{{cite journal | |||
|last=Fermi |first=E. | |||
|year=1930 | |||
|title=Über die magnetischen Momente der Atomkerne | |||
|journal=[[Zeitschrift für Physik]] | |||
|volume=60 |issue=5–6 |page=320 | |||
|arxiv= | |||
|bibcode= 1930ZPhy...60..320F | |||
|doi= 10.1007/BF01339933 | |||
}}</ref> A classical derivation of this term is contained in [[J.D. Jackson]].<ref> | |||
{{cite book | |||
|last=Jackson |first=J. D. | |||
|year=1998 | |||
|title=Classical Electrodynamics | |||
|page=184 |edition=3rd | |||
|publisher=[[John Wiley & Sons|Wiley]] | |||
|isbn=978-0471309321 | |||
}}</ref> In short the classical energy may be written in terms of the energy of one [[magnetic dipole]] moment in the magnetic field '''B'''''(r)'' of another. This field acquires a simple expression when the distance ''r'' between the two moments goes to zero, since: | |||
:<math> \int_{S(r)} B(r) d^3r = -\frac 2 3 \mu_0 \boldsymbol{\mu} </math> | |||
==References== | |||
{{Reflist}} | |||
[[Category:Magnetostatics]] | |||
[[Category:Magnetism]] | |||
[[Category:Electric and magnetic fields in matter]] | |||
Revision as of 18:35, 8 March 2013
The Fermi contact interaction is the magnetic interaction between an electron and an atomic nucleus when the electron is inside that nucleus.
The parameter is usually described with the symbol A and the units are usually megahertz. The magnitude of A is given by this relationship:
and
where A is the energy of the interaction, μn is the nuclear magnetic moment, μe is the electron magnetic dipole moment, and Ψ(0) is the electron wavefunction at the nucleus.[1]
It has been pointed out that it is an ill-defined problem because the standard formulation assumes that the nucleus has a magnetic dipolar moment, which is not always the case.[2]
Use in magnetic resonance spectroscopy
Within an atom, only s-orbitals have non-zero electron density at the nucleus, so the contact interaction only occurs for s-electrons. Its major manifestation is in electron paramagnetic resonance and nuclear magnetic resonance spectroscopies, where it is responsible for the appearance of isotropic hyperfine coupling. Roughly, the magnitude of A indicates the extent to which the unpaired spin resides on the atom. Thus, knowledge of the A values allows one to map the singly occupied molecular orbital.[3]
History
The interaction was first derived by Enrico Fermi in 1930.[4] A classical derivation of this term is contained in J.D. Jackson.[5] In short the classical energy may be written in terms of the energy of one magnetic dipole moment in the magnetic field B(r) of another. This field acquires a simple expression when the distance r between the two moments goes to zero, since:
References
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- ↑
One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting
In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang
Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.
A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running
The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang - ↑
One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting
In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang
Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.
A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running
The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang - ↑
20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
My blog: http://www.primaboinca.com/view_profile.php?userid=5889534 - ↑
One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting
In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang
Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules
Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.
A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running
The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more
There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang - ↑
20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
My blog: http://www.primaboinca.com/view_profile.php?userid=5889534