Airy wave theory: Difference between revisions

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'''Palierne equation''' connects the [[dynamic modulus]] of [[emulsion]]s with the dynamic modulus of the two [[Phase (matter)|phases]], size of the droplets and the interphase [[surface tension]]. The equation can also be used for [[Suspension (chemistry)|suspensions]] of [[viscoelastic]] solid particles in viscoelastic fluids.<ref name=Pal>{{cite journal |doi=10.1002/pen.21065 |last=Pal |first=Rajinder |title=A New Viscoelastic Model for Emulsions and Suspensions|journal=Polymer Engineering and Science |volume=48 |year=2008 |issue=7 |month=July |pages=1250..1253}}</ref> The equation is named after French [[rheology|rheologist]] [[Jean-François Palierne]] who has proposed the equation in 1991.<ref>{{cite journal |doi=10.1007/BF01331356 |last=Palierne |first=Jean-François |title=Linear Rheology of viscoelastic emulsions with interfacial tension|journal=Rheologica Acta |volume=29 |issue=3 |year=1991 |pages=204}}</ref>


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For the dilute emulsions Palierne equation looks like:
:<math>G^*=G^*_m(1+5\phi H^*)</math>
where <math>G^*</math> is the dynamic modulus of the emulsion, <math>G^*_m</math> is the dynamic modulus of the continuous phase (matrix), <math>\phi</math> is the volume fraction of the disperse phase and the <math>H^*</math> is given as
:<math>H^*=\frac{(G^*_d-G^*_m)(19G^*_d+16G^*_m)+(4\sigma/R)(5G^*_d+2G^*_m)}{(2G^*_d+3G^*_m)(19G^*_d+16G^*_m)+(40\sigma/R)(G^*_d+G^*_m)}</math>
where <math>G^*_d</math> is the dynamic modulus of the disperse phase, <math>\sigma</math> is the surface tension between the phases and <math>R</math> is the [[radius]] of the droplets.<ref name=Pal/>
 
For the suspension of solid particles the value of <math>H^*</math> is given as<ref name=Pal/>
:<math>H^*=\frac{G^*_d-G^*_m}{2G^*_d+3G^*_m}</math>
 
The Palierne equation is usually extended for the finite volume concentrations of the disperse phase <math>\phi</math> as:<ref name=Pal/>
:<math>G^*=G^*_m\frac{1+3\phi H^*}{1 - 2 \phi H^*}</math>
 
==References==
{{reflist}}
 
[[Category:Non-Newtonian fluids]]
[[Category:Colloidal chemistry]]
[[Category:Composite materials]]

Revision as of 07:08, 17 December 2013

Palierne equation connects the dynamic modulus of emulsions with the dynamic modulus of the two phases, size of the droplets and the interphase surface tension. The equation can also be used for suspensions of viscoelastic solid particles in viscoelastic fluids.[1] The equation is named after French rheologist Jean-François Palierne who has proposed the equation in 1991.[2]

For the dilute emulsions Palierne equation looks like:

G*=Gm*(1+5ϕH*)

where G* is the dynamic modulus of the emulsion, Gm* is the dynamic modulus of the continuous phase (matrix), ϕ is the volume fraction of the disperse phase and the H* is given as

H*=(Gd*Gm*)(19Gd*+16Gm*)+(4σ/R)(5Gd*+2Gm*)(2Gd*+3Gm*)(19Gd*+16Gm*)+(40σ/R)(Gd*+Gm*)

where Gd* is the dynamic modulus of the disperse phase, σ is the surface tension between the phases and R is the radius of the droplets.[1]

For the suspension of solid particles the value of H* is given as[1]

H*=Gd*Gm*2Gd*+3Gm*

The Palierne equation is usually extended for the finite volume concentrations of the disperse phase ϕ as:[1]

G*=Gm*1+3ϕH*12ϕH*

References

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