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Much insight in [[quantum mechanics]] can be gained from understanding the solutions to the time-dependent non-relativistic [[Schrödinger equation]] in an appropriate [[configuration space]]. In vector Cartesian coordinates <math>\mathbf{r}</math>, the equation takes the form
 
:<math>
H \psi\left(\mathbf{r}, t\right) = \left(T + V\right) \, \psi\left(\mathbf{r}, t\right) =
\left[ - \frac{\hbar^2}{2m} \nabla^2 + V\left(\mathbf{r}\right) \right] \psi\left(\mathbf{r}, t\right) = i\hbar \frac{\partial\psi\left(\mathbf{r}, t\right)}{\partial t}
</math>
 
in which <math>\psi</math> is the [[wavefunction]] of the system, H is the [[Hamiltonian operator]], and T and V are the operators for the [[kinetic energy]] and [[potential energy]], respectively. (Common forms of these operators appear in the square brackets.) The quantity ''t'' is the time. [[Stationary state]]s of this equation are found by solving the [[eigenvalue]]-[[eigenfunction]] (time-independent) form of the Schrödinger equation,
 
:<math>
\left[ - \frac{\hbar^2}{2m} \nabla^2 + V\left(\mathbf{r}\right) \right] \psi\left(\mathbf{r}\right) = E \psi \left(\mathbf{r}\right)
</math>
 
or any equivalent formulation of this equation in a different coordinate system other than Cartesian coordinates. For example, systems with spherical symmetry are simplified when expressed with [[spherical coordinates]]. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. Fortunately, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies can be found. These '''quantum-mechanical systems with analytical solutions''' are listed below, and are quite useful for teaching and gaining intuition about quantum mechanics.
 
== Solvable systems ==
 
*The [[free particle]]
*The [[delta potential]]
*The [[particle in a box]] / [[infinite potential well]]
*The [[finite potential well]]
*The [[Airy function|One-dimensional triangular potential]]
*The [[particle in a ring]] or [[ring wave guide]]
*The [[particle in a spherically symmetric potential]]
*The [[quantum harmonic oscillator]]
*The [[hydrogen atom]] or [[hydrogen-like atom]]
*The [[particle in a one-dimensional lattice (periodic potential)]]
*The [[Morse potential]]
*The [[step potential]]
*The [[Rigid_rotor#Quantum_mechanical_linear_rigid_rotor|linear rigid rotor]]
*The [[Rigid_rotor#Quantum_mechanical_rigid_rotor|symmetric top]]
*The [[Hooke's atom]]
*The [[Spherium]]
*Zero range interaction in a harmonic trap<ref>http://www.springerlink.com/content/k86t52r653522rk6/</ref>
*The [[Quantum pendulum]]
*The [[Rectangular potential barrier]]
 
==References==
{{reflist}}
== See also ==
* [[List of quantum-mechanical potentials]] &ndash; a list of physically relevant potentials without regard to analytic solubility
* [[List of integrable models]]
 
== Reading materials ==
 
* {{cite book
  | last = Mattis
  | first = Daniel C.
  | authorlink = Daniel C. Mattis
  | title = The Many-Body Problem: An Encyclopedia of Exactly Solved Models in One Dimension
  | publisher = [[World Scientific]]
  | date = 1993
  | isbn = 981-02-0975-4}}
 
[[Category:Quantum mechanics]]
[[Category:Quantum models]]
[[Category:Physics-related lists|Quantum-mechanical systems with analytical solutions]]

Revision as of 01:29, 9 January 2013

Much insight in quantum mechanics can be gained from understanding the solutions to the time-dependent non-relativistic Schrödinger equation in an appropriate configuration space. In vector Cartesian coordinates r, the equation takes the form

Hψ(r,t)=(T+V)ψ(r,t)=[22m2+V(r)]ψ(r,t)=iψ(r,t)t

in which ψ is the wavefunction of the system, H is the Hamiltonian operator, and T and V are the operators for the kinetic energy and potential energy, respectively. (Common forms of these operators appear in the square brackets.) The quantity t is the time. Stationary states of this equation are found by solving the eigenvalue-eigenfunction (time-independent) form of the Schrödinger equation,

[22m2+V(r)]ψ(r)=Eψ(r)

or any equivalent formulation of this equation in a different coordinate system other than Cartesian coordinates. For example, systems with spherical symmetry are simplified when expressed with spherical coordinates. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. Fortunately, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies can be found. These quantum-mechanical systems with analytical solutions are listed below, and are quite useful for teaching and gaining intuition about quantum mechanics.

Solvable systems

References

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See also

Reading materials

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