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In [[physics]], the '''thermal de Broglie wavelength''' (<math>\Lambda</math>) is roughly the average [[de Broglie wavelength]] of the gas particles in an ideal gas at the specified temperature. We can take the [[mean inter-particle distance|average interparticle spacing]] in the gas to be approximately {{math|(''V''/''N'')<sup>1/3</sup>}} where {{mvar|V}} is the volume and {{mvar|N}} is the number of particles. When the thermal de Broglie wavelength is much smaller than the interparticle distance, the gas can be considered to be a classical or [[Maxwell–Boltzmann statistics|Maxwell–Boltzmann]] gas. On the other hand, when the thermal de Broglie wavelength is on the order of or larger than the interparticle distance, quantum effects will dominate and the gas must be treated as a [[Fermi gas]] or a [[Bose gas]], depending on the nature of the gas particles. The critical temperature is the transition point between these two regimes, and at this critical temperature, the thermal wavelength will be approximately equal to the interparticle distance. That is, the quantum nature of the gas will be evident for
<!--
:<math>
\frac{V}{N\Lambda^3} \le 1 \ , {\rm or}
</math>
-->
:<math>
  \displaystyle
  \frac{V}{N\Lambda^3} \le 1
  \ , {\rm or} \
  \left( \frac{V}{N} \right)^{1/3} \le \Lambda
</math>


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i.e., when the interparticle distance is less than the thermal de Broglie wavelength;
in this case the gas will obey [[Bose–Einstein statistics]] or [[Fermi–Dirac statistics]],
whichever is appropriate. This is for example the case for electrons in a typical metal at ''T'' = 300 [[Kelvin|K]], where the electron gas obeys [[Fermi–Dirac statistics]], or in a [[Bose–Einstein condensate]].
On the other hand, for
<!--
:<math>\frac{V}{N\Lambda^3} \gg 1</math>
-->
:<math>
  \displaystyle
  \frac{V}{N\Lambda^3} \gg 1
  \ , {\rm or} \
  \left( \frac{V}{N} \right)^{1/3} \gg \Lambda
</math>
 
i.e., when the interparticle distance is much larger than the thermal de Broglie wavelength,
the gas will obey [[Maxwell–Boltzmann statistics]].<ref name="Kittel">{{cite book|title= Thermal Physics|edition=2|publisher=,W. H. Freeman|year=1980|page=73|author=Charles Kittel|author2=Herbert Kroemer|isbn=978-0716710882}}</ref> Such is the case for [[Neutron temperature|Thermal Neutron]] produced by a [[Neutron source]].
 
==Massive Particles==
 
For a free [[ideal gas]] of massive particles (with no internal degrees of freedom) in equilibrium, the thermal de Broglie wavelength can be obtained through the standard [[Matter wave|de Broglie wavelength]]:
:<math>\Lambda = \frac{h}{p}</math>, with the substitution of the momentum (<math>p</math>) by the [[Kinetic energy]] <math>E_K = \frac{p^2}{2m}</math>:
 
:<math>\Lambda = \frac{h}{\sqrt{2mE_K}}</math>.
 
Then in the quantum mechanical case the average [[Kinetic energy]] of free particles is <math>E_K=\pi k_B T</math>.
:<math>\Lambda = \sqrt{\frac{ h^2}{ 2\pi mkT}} = \frac{h}{\sqrt{2\pi mkT}},</math>
 
In the classical case the average [[Kinetic energy]] of free particles is <math>E_K=\frac{3}{2} k_B T</math>.
:<math>\Lambda = \frac{h}{\sqrt{3 mkT}},</math>
 
where {{math|''h''}} is the [[Planck constant]], {{mvar|m}} is the [[mass]] of a gas particle, {{mvar|k}} is the [[Boltzmann constant]], and {{mvar|T}} is the [[temperature]] of the gas.<ref name="Kittel"/>
 
==Massless particles==
 
For a massless particle, the thermal wavelength may be defined as:
 
:<math>\Lambda= \frac{ch}{2 \pi^{1/3} k T}</math>
 
where ''c&nbsp;'' is the speed of light. As with the thermal wavelength for massive particles, this is of the order of the average wavelength of the particles in the gas and defines a critical point at which quantum effects begin to dominate. For example, when observing the long-wavelength spectrum of [[black body]] radiation, the "classical" [[Rayleigh–Jeans law]] can be applied, but when the observed wavelengths approach the thermal wavelength of the photons in the [[black body]] radiator, the "quantum" [[Planck's law of black body radiation|Planck's law]] must be used.
 
==General definition of the thermal wavelength==
 
A general definition of the thermal wavelength for an ideal quantum gas in
any number of dimensions and for a generalized relationship between energy and
momentum (dispersion relationship) has been given by Yan (Yan 2000). It is of practical importance, since there are many experimental situations with different dimensionality and dispersion relationships. If {{mvar|n}} is the number of dimensions, and the relationship
between energy&nbsp;({{mvar|E}}) and momentum&nbsp;({{mvar|p}}) is given by:
 
:<math>E=ap^s\,</math>
 
where {{mvar|a}} and {{mvar|s}} are constants, then the thermal wavelength is defined as:
 
:<math>
\Lambda=\frac{h}{\sqrt{\pi}}\left(\frac{a}{kT}\right)^{1/s}
\left[\frac{\Gamma(n/2+1)}{\Gamma(n/s+1)}\right]^{1/n}
</math>
 
where Γ is the [[Gamma function]]. For example, in the usual case of massive
particles in a 3-D gas we have {{math|1=''n'' = 3 }}, and {{math|1=''E'' = ''p''<sup>2</sup>/2''m''}} which gives
the above results for massive particles. For massless particles in a 3-D gas,
we have {{math|1=''n'' = 3 }}, and {{math|1=''E'' = ''p c''}} which gives the above results for massless particles.
 
==References==
 
<references/>
* Zijun Yan, "General thermal wavelength and its applications", Eur. J. Phys. 21 (2000) 625–631. http://www.iop.org/EJ/article/0143-0807/21/6/314/ej0614.pdf
* {{cite web |url=http://clesm.mae.ufl.edu/wiki.pub/index.php/Configuration_integral_(statistical_mechanics) |title=Configuration_integral_(statistical_mechanics) |accessdate=2008-10-12 |last=Vu-Quoc |first=Loc  }}
 
[[Category:Statistical mechanics]]

Latest revision as of 16:13, 25 December 2013

In physics, the thermal de Broglie wavelength () is roughly the average de Broglie wavelength of the gas particles in an ideal gas at the specified temperature. We can take the average interparticle spacing in the gas to be approximately Buying, selling and renting HDB and personal residential properties in Singapore are simple and transparent transactions. Although you are not required to engage a real property salesperson (generally often known as a "public listed property developers In singapore agent") to complete these property transactions, chances are you'll think about partaking one if you are not accustomed to the processes concerned.

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Another method by way of which you could find out whether the agent is sweet is by checking the feedback, of the shoppers, on the website. There are various individuals would publish their comments on the web site of the Singapore property agent. You can take a look at these feedback and the see whether it will be clever to hire that specific Singapore property agent. You may even get in contact with the developer immediately. Many Singapore property brokers know the developers and you may confirm the goodwill of the agent by asking the developer. where Template:Mvar is the volume and Template:Mvar is the number of particles. When the thermal de Broglie wavelength is much smaller than the interparticle distance, the gas can be considered to be a classical or Maxwell–Boltzmann gas. On the other hand, when the thermal de Broglie wavelength is on the order of or larger than the interparticle distance, quantum effects will dominate and the gas must be treated as a Fermi gas or a Bose gas, depending on the nature of the gas particles. The critical temperature is the transition point between these two regimes, and at this critical temperature, the thermal wavelength will be approximately equal to the interparticle distance. That is, the quantum nature of the gas will be evident for

i.e., when the interparticle distance is less than the thermal de Broglie wavelength; in this case the gas will obey Bose–Einstein statistics or Fermi–Dirac statistics, whichever is appropriate. This is for example the case for electrons in a typical metal at T = 300 K, where the electron gas obeys Fermi–Dirac statistics, or in a Bose–Einstein condensate. On the other hand, for

i.e., when the interparticle distance is much larger than the thermal de Broglie wavelength, the gas will obey Maxwell–Boltzmann statistics.[1] Such is the case for Thermal Neutron produced by a Neutron source.

Massive Particles

For a free ideal gas of massive particles (with no internal degrees of freedom) in equilibrium, the thermal de Broglie wavelength can be obtained through the standard de Broglie wavelength:

, with the substitution of the momentum () by the Kinetic energy :
.

Then in the quantum mechanical case the average Kinetic energy of free particles is .

In the classical case the average Kinetic energy of free particles is .

where Buying, selling and renting HDB and personal residential properties in Singapore are simple and transparent transactions. Although you are not required to engage a real property salesperson (generally often known as a "public listed property developers In singapore agent") to complete these property transactions, chances are you'll think about partaking one if you are not accustomed to the processes concerned.

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A wholly owned subsidiary of SLP Worldwide, SLP Realty houses 900 associates to service SLP's fast rising portfolio of residential tasks. Real estate is a human-centric trade. Apart from offering comprehensive coaching applications for our associates, SLP Realty puts equal emphasis on creating human capabilities and creating sturdy teamwork throughout all ranges of our organisational hierarchy. Worldwide Presence At SLP International, our staff of execs is pushed to make sure our shoppers meet their enterprise and investment targets. Under is an inventory of some notable shoppers from completely different industries and markets, who've entrusted their real estate must the expertise of SLP Worldwide.

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Another method by way of which you could find out whether the agent is sweet is by checking the feedback, of the shoppers, on the website. There are various individuals would publish their comments on the web site of the Singapore property agent. You can take a look at these feedback and the see whether it will be clever to hire that specific Singapore property agent. You may even get in contact with the developer immediately. Many Singapore property brokers know the developers and you may confirm the goodwill of the agent by asking the developer. is the Planck constant, Template:Mvar is the mass of a gas particle, Template:Mvar is the Boltzmann constant, and Template:Mvar is the temperature of the gas.[1]

Massless particles

For a massless particle, the thermal wavelength may be defined as:

where is the speed of light. As with the thermal wavelength for massive particles, this is of the order of the average wavelength of the particles in the gas and defines a critical point at which quantum effects begin to dominate. For example, when observing the long-wavelength spectrum of black body radiation, the "classical" Rayleigh–Jeans law can be applied, but when the observed wavelengths approach the thermal wavelength of the photons in the black body radiator, the "quantum" Planck's law must be used.

General definition of the thermal wavelength

A general definition of the thermal wavelength for an ideal quantum gas in any number of dimensions and for a generalized relationship between energy and momentum (dispersion relationship) has been given by Yan (Yan 2000). It is of practical importance, since there are many experimental situations with different dimensionality and dispersion relationships. If Template:Mvar is the number of dimensions, and the relationship between energy (Template:Mvar) and momentum (Template:Mvar) is given by:

where Template:Mvar and Template:Mvar are constants, then the thermal wavelength is defined as:

where Γ is the Gamma function. For example, in the usual case of massive particles in a 3-D gas we have Buying, selling and renting HDB and personal residential properties in Singapore are simple and transparent transactions. Although you are not required to engage a real property salesperson (generally often known as a "public listed property developers In singapore agent") to complete these property transactions, chances are you'll think about partaking one if you are not accustomed to the processes concerned.

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Another method by way of which you could find out whether the agent is sweet is by checking the feedback, of the shoppers, on the website. There are various individuals would publish their comments on the web site of the Singapore property agent. You can take a look at these feedback and the see whether it will be clever to hire that specific Singapore property agent. You may even get in contact with the developer immediately. Many Singapore property brokers know the developers and you may confirm the goodwill of the agent by asking the developer. which gives the above results for massive particles. For massless particles in a 3-D gas, we have Buying, selling and renting HDB and personal residential properties in Singapore are simple and transparent transactions. Although you are not required to engage a real property salesperson (generally often known as a "public listed property developers In singapore agent") to complete these property transactions, chances are you'll think about partaking one if you are not accustomed to the processes concerned.

Professional agents are readily available once you need to discover an condominium for hire in singapore In some cases, landlords will take into account you more favourably in case your agent comes to them than for those who tried to method them by yourself. You need to be careful, nevertheless, as you resolve in your agent. Ensure that the agent you are contemplating working with is registered with the IEA – Institute of Estate Brokers. Whereas it might sound a hassle to you, will probably be worth it in the end. The IEA works by an ordinary algorithm and regulations, so you'll protect yourself in opposition to probably going with a rogue agent who prices you more than they should for his or her service in finding you an residence for lease in singapore.

There isn't any deal too small. Property agents who are keen to find time for any deal even if the commission is small are the ones you want on your aspect. Additionally they present humbleness and might relate with the typical Singaporean higher. Relentlessly pursuing any deal, calling prospects even without being prompted. Even if they get rejected a hundred times, they still come again for more. These are the property brokers who will find consumers what they need eventually, and who would be the most successful in what they do. 4. Honesty and Integrity

This feature is suitable for you who need to get the tax deductions out of your PIC scheme to your property agency firm. It's endorsed that you visit the correct site for filling this tax return software. This utility must be submitted at the very least yearly to report your whole tax and tax return that you're going to receive in the current accounting 12 months. There may be an official website for this tax filling procedure. Filling this tax return software shouldn't be a tough thing to do for all business homeowners in Singapore.

A wholly owned subsidiary of SLP Worldwide, SLP Realty houses 900 associates to service SLP's fast rising portfolio of residential tasks. Real estate is a human-centric trade. Apart from offering comprehensive coaching applications for our associates, SLP Realty puts equal emphasis on creating human capabilities and creating sturdy teamwork throughout all ranges of our organisational hierarchy. Worldwide Presence At SLP International, our staff of execs is pushed to make sure our shoppers meet their enterprise and investment targets. Under is an inventory of some notable shoppers from completely different industries and markets, who've entrusted their real estate must the expertise of SLP Worldwide.

If you're looking for a real estate or Singapore property agent online, you merely need to belief your instinct. It is because you don't know which agent is sweet and which agent will not be. Carry out research on a number of brokers by looking out the internet. As soon as if you find yourself certain that a selected agent is dependable and trustworthy, you'll be able to choose to utilize his partnerise find you a house in Singapore. More often than not, a property agent is considered to be good if she or he places the contact data on his web site. This is able to imply that the agent does not thoughts you calling them and asking them any questions regarding properties in Singapore. After chatting with them you too can see them of their office after taking an appointment.

Another method by way of which you could find out whether the agent is sweet is by checking the feedback, of the shoppers, on the website. There are various individuals would publish their comments on the web site of the Singapore property agent. You can take a look at these feedback and the see whether it will be clever to hire that specific Singapore property agent. You may even get in contact with the developer immediately. Many Singapore property brokers know the developers and you may confirm the goodwill of the agent by asking the developer., and Buying, selling and renting HDB and personal residential properties in Singapore are simple and transparent transactions. Although you are not required to engage a real property salesperson (generally often known as a "public listed property developers In singapore agent") to complete these property transactions, chances are you'll think about partaking one if you are not accustomed to the processes concerned.

Professional agents are readily available once you need to discover an condominium for hire in singapore In some cases, landlords will take into account you more favourably in case your agent comes to them than for those who tried to method them by yourself. You need to be careful, nevertheless, as you resolve in your agent. Ensure that the agent you are contemplating working with is registered with the IEA – Institute of Estate Brokers. Whereas it might sound a hassle to you, will probably be worth it in the end. The IEA works by an ordinary algorithm and regulations, so you'll protect yourself in opposition to probably going with a rogue agent who prices you more than they should for his or her service in finding you an residence for lease in singapore.

There isn't any deal too small. Property agents who are keen to find time for any deal even if the commission is small are the ones you want on your aspect. Additionally they present humbleness and might relate with the typical Singaporean higher. Relentlessly pursuing any deal, calling prospects even without being prompted. Even if they get rejected a hundred times, they still come again for more. These are the property brokers who will find consumers what they need eventually, and who would be the most successful in what they do. 4. Honesty and Integrity

This feature is suitable for you who need to get the tax deductions out of your PIC scheme to your property agency firm. It's endorsed that you visit the correct site for filling this tax return software. This utility must be submitted at the very least yearly to report your whole tax and tax return that you're going to receive in the current accounting 12 months. There may be an official website for this tax filling procedure. Filling this tax return software shouldn't be a tough thing to do for all business homeowners in Singapore.

A wholly owned subsidiary of SLP Worldwide, SLP Realty houses 900 associates to service SLP's fast rising portfolio of residential tasks. Real estate is a human-centric trade. Apart from offering comprehensive coaching applications for our associates, SLP Realty puts equal emphasis on creating human capabilities and creating sturdy teamwork throughout all ranges of our organisational hierarchy. Worldwide Presence At SLP International, our staff of execs is pushed to make sure our shoppers meet their enterprise and investment targets. Under is an inventory of some notable shoppers from completely different industries and markets, who've entrusted their real estate must the expertise of SLP Worldwide.

If you're looking for a real estate or Singapore property agent online, you merely need to belief your instinct. It is because you don't know which agent is sweet and which agent will not be. Carry out research on a number of brokers by looking out the internet. As soon as if you find yourself certain that a selected agent is dependable and trustworthy, you'll be able to choose to utilize his partnerise find you a house in Singapore. More often than not, a property agent is considered to be good if she or he places the contact data on his web site. This is able to imply that the agent does not thoughts you calling them and asking them any questions regarding properties in Singapore. After chatting with them you too can see them of their office after taking an appointment.

Another method by way of which you could find out whether the agent is sweet is by checking the feedback, of the shoppers, on the website. There are various individuals would publish their comments on the web site of the Singapore property agent. You can take a look at these feedback and the see whether it will be clever to hire that specific Singapore property agent. You may even get in contact with the developer immediately. Many Singapore property brokers know the developers and you may confirm the goodwill of the agent by asking the developer. which gives the above results for massless particles.

References

  1. 1.0 1.1 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534