|
|
| Line 1: |
Line 1: |
| {{Use dmy dates|date=July 2013}}
| | Hi there, I am Alyson Pomerleau and I think it sounds fairly great when you say it. Kentucky is where I've usually been living. What me and my family adore is doing ballet but I've been using on new things lately. Invoicing is my profession.<br><br>My page: love psychics ([http://formalarmour.com/index.php?do=/profile-26947/info/ formalarmour.com]) |
| <!-- To obtain a blank version of this page, type subst:chembox supplement inside of double curly braces, {{}}, and save the page -->
| |
| This page provides supplementary chemical data on [[chloromethane]]. <!-- replace with proper wikilink -->
| |
| | |
| == Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source such as [http://www2.siri.org/msds/index.php SIRI], and follow its directions. MSDS for chloromethane is available at [http://www2.siri.org/msds/mf/cards/file/0419.html Safety Information Resources, inc.]
| |
| | |
| == Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | Structure and properties
| |
| |-
| |
| | [[Index of refraction]],<ref name="inchem">{{Cite web|url=http://www.inchem.org/documents/pims/chemical/metchlor.htm|title=Methyl Chloride|publisher=Inchem|accessdate=30 May 2007}}</ref> ''n''<sub>D</sub>
| |
| | 1.3389 <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Abbe number]]
| |
| | ? <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Dielectric constant]],<ref>{{Cite web|url=http://www.asiinstr.com/technical/Dielectric%20Constants.htm|title=Dielectric Constants Chart|publisher=ASI Instruments|accessdate=30 May 2007}}</ref> ε<sub>r</sub>
| |
| | 12.9 ε<sub>0</sub> at 25 °C <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Bond strength]]
| |
| | ? <!-- Specify which bond. Please omit if not applicable -->
| |
| |-
| |
| | [[Bond length]]
| |
| | ? <!-- Specify which bond. Please omit if not applicable -->
| |
| |-
| |
| | [[Bond angle]]
| |
| | ? <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
| |
| |-
| |
| | [[Molecular dipole moment|Dipole moment]]
| |
| | 1.9 D <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
| |
| |-
| |
| | [[Magnetic susceptibility]]
| |
| | ? <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Acentric factor]]
| |
| | 0.153 <!-- Please omit if not applicable -->
| |
| |-
| |
| | Critical compressibility
| |
| | 0.268247 <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Compressibility factor]]
| |
| | 0.985 <!-- Please omit if not applicable -->
| |
| |-
| |
| | [[Density]] <ref>[http://encyclopedia.airliquide.com/encyclopedia.asp?LanguageID=11&CountryID=19&Formula=&GasID=18&UNNumber= Air Liquide Gas Encyclopedia]</ref>
| |
| | 1002.9 kg/m<sup>3</sup> at -24.2 °C (liquid)<br/>2.55 kg/m<sup>3</sup> at -24.2 °C (gas)<br/>2.22 kg/m<sup>3</sup> at 0 °C (gas)<br/>2.134 kg/m<sup>3</sup> at 15 °C (gas)
| |
| |-
| |
| | [[Surface tension]]<ref>''Lange's Handbook of Chemistry'', 10th ed. pp 1661-1663</ref>
| |
| | 19.5 dyn/cm at 0°C<br>17.8 dyn/cm at 10°C<br>16.2 dyn/cm at 20°C
| |
| |-
| |
| | [[Viscosity]]<ref name="cheric_p">{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|publisher=Chemical Engineering Research Information Center|format=Queriable database|accessdate=30 May 2007}}</ref>
| |
| | 0.2280 mPa·s at 0°C<br>0.1784 mPa·s at 20°C<br>0.1440 mPa·s at 40°C
| |
| |-
| |
| | [[Thermal conductivity]]
| |
| | 10.5 mW/(m·K) at 0 °C
| |
| |-
| |
| |}
| |
| | |
| == Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | Phase behavior
| |
| |-
| |
| | [[Triple point]]
| |
| | 175.43 K (–97.72 °C), 870 Pa
| |
| |-
| |
| | [[Critical point (chemistry)|Critical point]]
| |
| | 416 K (143 °C), 6714.4 kPa
| |
| |-
| |
| | [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| |
| | 6.43 kJ/mol
| |
| |-
| |
| | [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| |
| | 36.66 J/(mol·K)
| |
| |-
| |
| | [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| |
| | 21.535 kJ/mol at –24.21°C<br>20.09 kJ/mol at 20°C
| |
| |-
| |
| | [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| |
| | 86.51 J/(mol·K) at –24.21°C
| |
| |-
| |
| ! {{chembox header}} | Solid properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| |
| | ? kJ/mol
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| |
| | ? J/(mol K)
| |
| |-
| |
| | [[Heat capacity]], ''c<sub>p</sub>''
| |
| | ? J/(mol K)
| |
| |-
| |
| ! {{chembox header}} | Liquid properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| |
| | –86.37 kJ/mol at 25°C
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| |
| | 140.08 J/(mol K)
| |
| |-
| |
| | [[Heat capacity]], ''c<sub>p</sub>''
| |
| | 81.2 J/(mol K) at 15°C
| |
| |-
| |
| ! {{chembox header}} | Gas properties
| |
| |-
| |
| | [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| |
| | –83.68 kJ/mol
| |
| |-
| |
| | [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| |
| | 234.36 J/(mol K) at 100 kPa
| |
| |-
| |
| | [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| |
| | –764.0 kJ/mol
| |
| |-
| |
| | [[Heat capacity]], ''c<sub>p</sub>''
| |
| | 40.70 J/(mol K) at 25°C
| |
| |-
| |
| | [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522-1524</ref>
| |
| | a = 757.0 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.06483 liter per mole
| |
| |-
| |
| |}
| |
| | |
| ==Vapor pressure of liquid==
| |
| {| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
| |
| |-
| |
| | {{chembox header}} | '''P in mm Hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 || 45600
| |
| |-
| |
| | {{chembox header}} | '''T in °C''' || — || –92.4 || –76.0 || –63.0 || –38.0 || –24.0 || –6.4 || 22.0 || 47.3 || 77.3 || 113.8 || 137.5
| |
| |}
| |
| Table data obtained from ''CRC Handbook of Chemistry and Physics'' 44th ed.
| |
| | |
| [[Image:LogMethylChlorideVaporPresure.png|thumb|740px|left|'''log<sub>10</sub> of Methyl Chloride vapor pressure.''' Uses formula: <math>\scriptstyle \log_e P_{mmHg} =</math><math>\scriptstyle \log_e (\frac {760} {101.325}) - 7.072977\log_e(T+273.15) - \frac {4094.935} {T+273.15} + 59.41150 + 1.092121 \times 10^{-5} (T+273.15)^2</math> obtained from CHERIC<ref name="cheric_p"/>]]{{Clear}}
| |
| | |
| == Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
| |
| | |
| {| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
| |
| ! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
| |
| |-
| |
| | [[Lambda-max|λ<sub>max</sub>]]
| |
| | ? [[Nanometre|nm]]
| |
| |-
| |
| | [[molar absorptivity|Extinction coefficient]], ε
| |
| | ?
| |
| |-
| |
| ! {{chembox header}} | [[Infrared|IR]]
| |
| |-
| |
| | Major absorption bands
| |
| | ? cm<sup>−1</sup>
| |
| |-
| |
| ! {{chembox header}} | [[NMR Spectroscopy|NMR]]
| |
| |-
| |
| | [[Proton NMR]] <!-- Link to image of spectrum -->
| |
| |
| |
| |-
| |
| | [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| |
| |
| |
| |-
| |
| | Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| |
| |
| |
| |-
| |
| ! {{chembox header}} | [[Mass Spectrometry|MS]]
| |
| |-
| |
| | Masses of <br>main fragments
| |
| | <!-- Give list of major fragments -->
| |
| |-
| |
| |}
| |
| | |
| ==References==
| |
| <references/>
| |
| * {{Cite web|url=http://webbook.nist.gov/chemistry/|title=NIST Standard Reference Database}}
| |
| | |
| Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
| |
| | |
| [[wikipedia:Chemical infobox|Disclaimer]] applies.
| |
| | |
| {{DEFAULTSORT:Chloromethane (Data Page)}}
| |
| [[Category:Chemical data pages]]
| |