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The '''Cole–Cole equation''' is a [[relaxation]] model that is often used to describe [[dielectric relaxation]] in [[polymer]]s.
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It is given by the equation
:<math>
\varepsilon^*(\omega) - \varepsilon_\infty = \frac{\varepsilon_s - \varepsilon_\infty}{1+(i\omega\tau)^{1 - \alpha}}
</math>
where <math>\varepsilon^*</math> is the [[Dielectric constant#Complex permittivity|complex dielectric constant]], <math>\varepsilon_s</math> and <math>\varepsilon_\infty</math> are the "static" and "infinite frequency" dielectric constants, <math>\omega</math> is the [[angular frequency]] and <math>\tau</math> is a time constant.


The exponent parameter <math>\alpha</math>, which takes a value between 0 and 1, allows to describe different spectral shapes. When <math>\alpha=0</math>, the Cole-Cole model reduces to the [[Dielectric#Debye relaxation|Debye]] model. When <math>\alpha>0</math>, the relaxation is ''stretched'', i.e. it extends over a wider range on a logarithmic <math>\omega</math> scale than Debye relaxation.
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Cole-Cole relaxation constitutes a special case of [[Havriliak-Negami relaxation]] when the symmetry parameter (β) is equal to 1 - that is, when the relaxation peaks are symmetric. Another special case of Havriliak-Negami relaxation (β<1, α=0) is known as [[Cole-Davidson relaxation]], for an abridged and updated review of anomalous dielectric relaxation in dissored systems see Kalmykov.
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== References ==
  <li>[http://annuncianimali.altervista.org/index.php?page=item&id=133834 http://annuncianimali.altervista.org/index.php?page=item&id=133834]</li>
 
    
{{cite journal
  <li>[http://cerisier.info/spip.php?article25/ http://cerisier.info/spip.php?article25/]</li>
  | last1 = Cole
    
  | first1 = K.S.
  <li>[http://verdamilio.info/org/spip.php?article573/ http://verdamilio.info/org/spip.php?article573/]</li>
  | last2 = Cole
 
  | first2 = R.H.
</ul>
  | title = Dispersion and Absorption in Dielectrics - I Alternating Current Characteristics
  | journal = J. Chem. Phys.
  | year = 1941
  | volume = 9
  | pages = 341–352
  |bibcode = 1941JChPh...9..341C |doi = 10.1063/1.1750906 }}
 
{{cite journal
  | last1 = Cole
  | first1 = K.S.
  | last2 = Cole
  | first2 = R.H.
  | title = Dispersion and Absorption in Dielectrics - II Direct Current Characteristics
  | journal = Journal of Chemical Physics
  | year = 1942
  | volume = 10
  | pages = 98–105
  |bibcode = 1942JChPh..10...98C |doi = 10.1063/1.1723677 }}
 
{{cite journal
  | last1 = Kalmykov
  | first1 = Y.P.
   | last2 = Coffey
  | first2 = W.T.
   | last3 = Crothers
  | first3 = D.S.F.
  | last4 = Titov
  | first4 = S.V.
  | title = Microscopic Models for Dielectric Relaxation in Disordered Systems
  | journal = Physical Review E
   | year = 2004
  | volume = 70
   | pages = 041103
  |bibcode = |doi = 10.1063/1.1723677 }}
 
 
 
 
 
{{DEFAULTSORT:Cole-Cole equation}}
[[Category:Electric and magnetic fields in matter]]

Latest revision as of 04:16, 4 October 2014

Mbt Paris I think it was past 9pm

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