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[[File:Solid solution.svg|thumb|200px|'''Fig. 1''' A binary phase diagram displaying solid solutions over the full range of relative concentrations.]]
{{Quote box
|title = IUPAC definition
|quote = Solid in which components are compatible and form a unique phase.


''Note 1'': The definition “crystal containing a second constituent which fits into and<br/>is distributed in the lattice of the host crystal” given in refs.,<ref>{{cite book|title=Compendium of Chemical Terminology: IUPAC Recommendations|year=1997|publisher=Blackwell Science|isbn=0865426848|edition=2nd|editor=Alan D. MacNaught, Andrew R. Wilkinson}}</ref><ref>{{cite book|title=Compendium of Analytical Nomenclature (the "Orange Book")|year=1998|publisher=Blackwell Science|location=Oxford|isbn=0865426155}}</ref> is not general<br/>and, thus, is not recommended.
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''Note 2'': The expression is to be used to describe a solid phase containing<br/>more than one substance when, for convenience, one (or more) of the substances,<br/>called the solvent, is treated differently from the other substances, called solutes.
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''Note 3'': One or several of the components can be ''macromolecules''. Some of<br/>the other components can then act as plasticizers, i.e., as molecularly dispersed<br/>substances that decrease the glass-transition temperature at which the amorphous<br/>phase of a ''polymer'' is converted between glassy and rubbery states.
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''Note 4'': In pharmaceutical preparations, the concept of solid solution is often<br/>applied to the case of mixtures of ''drug'' and ''polymer''.
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''Note 5'': The number of drug molecules that do behave as solvent (plasticizer)<br/>of polymers is small.<ref>{{cite journal|title=Terminology for biorelated polymers and applications (IUPAC Recommendations 2012)|journal=[[Pure and Applied Chemistry]]|year=2012|volume=84|issue=2|pages=377–410|doi=10.1351/PAC-REC-10-12-04|url=http://pac.iupac.org/publications/pac/pdf/2012/pdf/8402x0377.pdf}}</ref>
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A '''solid solution''' is a [[solid]]-[[phase (matter)|state]] [[solution]] of one or more [[Solubility|solutes]] in a [[solvent]]. Such a [[mixture]] is considered a solution rather than a [[Chemical compound|compound]] when the [[crystal structure]] of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase. This often happens when the two elements (generally [[metal]]s) involved are close together on the [[periodic table]]; conversely, a chemical compound is generally a result of the non-proximity of the two metals involved on the periodic table.<ref>{{cite book |first=Alan Howard |last= Cottrell |authorlink=Alan Cottrell |title=An Introduction to Metallurgy |publisher=Institute of Materials |year=1967 |isbn=0-8448-0767-2}}</ref>
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The solid solution needs to be distinguished from a mechanical mixture of powdered solids like two salts, sugar and salt, etc. The mechanical mixtures have total or partial [[miscibility]] gap in solid state.
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Examples of solid solutions include crystallized salts from their liquid mixture, metal [[alloys]], moist solids. In the case of metal alloys [[intermetallic]] compounds occur frequently.


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The solute may incorporate into the solvent [[crystal lattice]] ''[[Crystallographic_defect#substit|substitutionally]]'', by replacing a solvent particle in the lattice, or ''[[Interstitial defect|interstitially]]'', by fitting into the space between solvent particles. Both of these types of solid solution affect the properties of the material by distorting the crystal lattice and disrupting the physical and electrical homogeneity of the solvent material.<ref>{{cite book |title=Materials Science and Engineering: An Introduction |first=William D. |last=Callister Jr. |edition=7th |publisher=John Wiley & Sons |year=2006 |isbn=0-471-35446-5}}</ref>
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Some mixtures will readily form solid solutions over a range of concentrations, while other mixtures will not form solid solutions at all. The propensity for any two substances to form a solid solution is a complicated matter involving the [[chemistry|chemical]], [[crystallography|crystallographic]], and [[quantum mechanics|quantum]] properties of the substances in question. Substitutional solid solutions, in accordance with the [[Hume-Rothery rules]], may form if the solute and solvent have:
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* Similar [[atomic radius|atomic radii]] (15% or less difference)
 
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The [[phase diagram]] in ''Fig. 1'' displays an [[alloy]] of two metals which forms a solid solution at all relative [[concentration]]s of the two species. In this case, the pure phase of each element is of the same crystal structure, and the similar properties of the two elements allow for unbiased substitution through the full range of relative concentrations.
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Solid solutions have important commercial and industrial applications, as such mixtures often have superior properties to pure materials. Many metal alloys are solid solutions. Even small amounts of solute can affect the electrical and physical properties of the solvent.
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[[File:Eutektikum new.svg|thumb|250px|'''Fig. 2''' This binary phase diagram shows two solid solutions: <math>\alpha</math> and <math>\beta</math>.]]
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The binary phase diagram in ''Fig. 2'' shows the phases of a mixture of two substances in varying concentrations, <math>A</math> and <math>B</math>. The region labeled "<math>\alpha</math>" is a solid solution, with <math>B</math> acting as the solute in a matrix of <math>A</math>. On the other end of the concentration scale, the region labeled "<math>\beta</math>" is also a solid solution, with <math>A</math> acting as the solute in a matrix of <math>B</math>. The large solid region in between the <math>\alpha</math> and <math>\beta</math> solid solutions, labeled "<math>\alpha</math> + <math>\beta</math>", is ''not'' a solid solution. Instead, an examination of the [[microstructure]] of a mixture in this range would reveal two phases — solid solution <math>A</math>-in-<math>B</math> and solid solution <math>B</math>-in-<math>A</math> would form separate phases, perhaps [[Lamellar structure|lamella]] or [[crystallite|grains]].
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In the phase diagram, at three different concentrations, the material will be solid until it's heated to its [[melting point]], and then (after adding the [[heat of fusion]]) become liquid at that same temperature:
* the unalloyed extreme left
* the unalloyed extreme right
* the dip in the center (the eutectic composition).


At other proportions, the material will enter a mushy or pasty phase until it warms up to being completely melted.
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The mixture at the dip point of the diagram is called a [[eutectic point|eutectic]] alloy. Lead-tin mixtures formulated at that point (37/63 mixture) are useful when soldering electronic components, particularly if done manually, since the solid phase is quickly entered as the solder cools. In contrast, when lead-tin mixtures were used to solder seams in automobile bodies a pasty state enabled a shape to be formed with a wooden paddle or tool, so a 70-30 lead to tin ratio was used. (Lead is being removed from such applications owing to its toxicity and consequent difficulty in recycling devices and components that include lead.)
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Take the alkali [[feldspar]] [[minerals]] for example, whose [[Endmember|end members]] are [[albite]], NaAlSi<sub>3</sub>O<sub>8</sub> and [[microcline]], KAlSi<sub>3</sub>O<sub>8</sub>. At high temperatures Na<sup>+</sup> and K<sup>+</sup> readily substitute for each other and so the minerals will form a solid solution, yet at low temperatures albite can only substitute a small amount of K<sup>+</sup> and the same applies for Na<sup>+</sup> in the microcline. This leads to exsolution where they will separate into two separate phases. In the case of the alkali feldspar minerals, thin white albite layers will alternate between typically pink microcline.<ref name="test" />
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{{reflist}}
{{Refbegin}}
* {{cite journal
| url = http://www.uni-graz.at/IEC-7/PDF-files/Chen.pdf
| author = Chen, Jing; Xu, Zhi-qin <!-- these are the only two authors mentioned in the reference -->
| coauthors = Chen, Z-Z.; Li, T-F.; Chen, F-Y. <!-- these other authors are not mentioned in the reference -->
| title = Pargasite and ilmenite exsolution texture in clinopyroxene from the Hujialing Garnet-Pyroxenite, Su-lu U.H.P. Terrane, Central China: A geodynamic Implication
| doi = 10.1127/0935-1221/2005/0017-0895
| journal = [[European Journal of Mineralogy]]
| date = December 2005
| volume = 17
| issue = 6
| pages = 895–903
}}
* {{cite web
| url = http://www.mines.utah.edu/~wmep/59298/592PDF/rlm2.pdf
| last = Petersen | first = U.
| title = Introduction to Ore Microscopy II; Mineral Paragenesis
}}
{{Refend}}


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