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In [[physics]], the '''Washburn's equation''' describes [[capillary action|capillary flow]] in a bundle of parallel cylindrical tubes; it is extended with some issues also to imbibition into [[porous]] materials. The equation is named after Edward Wight Washburn;<ref name=washburn>{{cite journal | author=Edward W. Washburn | title=The Dynamics of Capillary Flow| journal=Physical Review| year=1921| volume=17| page=273| issue=3|bibcode = 1921PhRv...17..273W |doi = 10.1103/PhysRev.17.273 }}</ref> also known as '''Lucas–Washburn equation''', considering that Richard Lucas<ref name=Lucas>{{cite journal | author=Lucas, R. | title=Ueber das Zeitgesetz des Kapillaren Aufstiegs von Flussigkeiten| journal=Kolloid Z.| year=1918| volume=23| page=15}}</ref> wrote a similar paper three years earlier, or the '''Bell-Cameron-Lucas-Washburn equation''', considering J.M. Bell and F.K. Cameron's discovery of the form of the equation fifteen years earlier.<ref name=BellCameron>{{cite journal | author=Bell, J.M. and Cameron, F.K. | title=The flow of liquids through capillary spaces |journal=J. Phys. Chem.| year=1906| volume=10|pages=658–674}}</ref>
Is actually a a strategy and on top of that battle activation where that you must manage your very own tribe and also protect it from punctures. You have so as to build constructions which may possibly provide protection for all your soldiers along with a person's instruction. First think straight on your protection and after its recently ended up taken treatment. Crucial to move forward which has the criminal offense plan of action. As well as Military facilities, you likewise require to keep in mind's eye the way your tribe is certainly going. For instance, collecting tactics as well as raising your own tribe could be the key to good improvements.<br><br>


In case of a fully wettable capillary, it is
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:<math>
L^2=\frac{\gamma Dt}{4\eta}</math>
 
where <math>t</math> is the time for a [[liquid]] of [[dynamic viscosity]] <math>\eta</math> and [[surface tension]] <math>\gamma</math> to penetrate a distance <math>L</math> into the capillary whose pore diameter is <math>D</math>.
In case of a porous materials many issues have been raised both about the physical meaning of the calculated pore diameter <math>D</math><ref name=Dullien>{{cite book | author=Dullien, F. A. L. | title=Porous Media: Fluid Transport and Pore Structure.|  year=1979| publisher=New York: Academic Press| isbn=0-12-223650-5}}</ref> and the real possibility to use this equation for the calculation of the contact angle of the solid.<ref name=Brugnara>{{cite book | last1=Marco| first1=Brugnara| last2=Claudio| first2=Della Volpe| last3=Stefano | first3=Siboni| chapter=Wettability of porous materials. II. Can we obtain the contact angle from the Washburn equation?| title=Contact Angle, Wettability and Adhesion| year=2006| publisher=Mass. VSP| editor=Mittal, K. L. }}</ref>
 
The equation is derived for capillary flow in a cylindrical tube in the absence of a [[gravitational field]], but according to physicist [[Len Fisher]] can be extremely accurate for more complex materials including biscuits (see [[dunk (biscuit)]]).  Following [[National biscuit dunking day]], some newspaper articles quoted the equation as ''Fisher's equation''. {{Citation needed|date=May 2010}}
 
In his [http://prola.aps.org/abstract/PR/v17/i3/p273_1 paper] from 1921 Washburn applies [[Poiseuille's law]] for fluid motion
in a circular tube. Inserting the expression for the differential volume in terms
of the length <math>l</math> of fluid in the tube <math>dV=\pi r^2 dl</math>,
one obtains
 
:<math>\frac{\delta l}{\delta t}=\frac{\sum P}{8 r^2 \eta l}(r^4 +4 \epsilon r^3)</math>
 
where <math>\sum P</math> is the sum over the participating pressures, such as the atmospheric pressure <math>P_A</math>, the hydrostatic pressure <math>P_h</math> and the equivalent pressure due to capillary forces <math>P_c</math>. <math>\eta</math> is the [[viscosity]] of the liquid, and <math>\epsilon</math> is the coefficient of slip, which is assumed to be 0 for [[wetting]] materials. <math>r</math> is the radius of the capillary. The pressures in turn
can be written as
 
:<math>P_h=h g \rho - l g \rho\sin\psi</math>
:<math>P_c=\frac{2\gamma}{r}\cos\phi</math>
 
where <math>\rho</math> is the density of the liquid and <math>\gamma</math> its [[surface tension]]. <math>\psi</math> is the angle of the tube with respect to the horizontal axis. <math>\phi</math> is the contact angle of the liquid on the capillary material.
Substituting these expressions leads to the first-order [[differential equation]] for
the distance the fluid penetrates into the tube <math>l</math>:
 
:<math>\frac{\delta l}{\delta t}=\frac{[P_A+g \rho (h-l\sin\psi)+\frac{2\gamma}{r}\cos\phi](r^4 +4 \epsilon r^3)}{8 r^2 \eta l}</math>
 
==Washburn's constant==
 
The '''Washburn constant''' may be included in Washburn's equation.
 
It is calculated as follows:
:<math>
{(10^4(um/cm)(1N/m^2))}/{(68947.6(dynes/cm^2))}=0.1450(38)</math><ref>Micromeritics, "Autopore IV User Manual", September (2000). Section B, Appendix D: Data Reduction, page D-1. ''(Note that the addition of 1N/m2 is not given in this reference, merely implied)''</ref><ref>Micromeritics, "A new method of interpolation and smooth curve fitting based on local procedures", Journal of the Association of Computing Machinery (1970). Volume 17(4), pp.589-602.</ref>
 
==References==
{{Reflist}}
 
{{DEFAULTSORT:Washburn's Equation}}
[[Category:Equations of fluid dynamics]]
[[Category:Porous media]]

Latest revision as of 13:10, 21 October 2014

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