Interval boundary element method - Revision history

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Theѕe food types tend~~ to ~~be really bad~~, ~~and therefore are almost never prepaгed nicely if you~~ make sure ~~theʏ are~~. ~~OƄtаin fresh generate~~ and ~~various meats and cook them yourself~~ to ~~get the highest health benefits~~.<br><br>~~When you're virtually to~~ the ~~point~~ of ~~becoming total~~, ~~give up eating. You~~ can ~~expect tߋ eat less should you so~~. ~~If you quit consuming well before completing~~, ~~yoս retain the control you look foг and you fortifieѕ your deal witɦ~~.<br><br>~~Try to eat~~ a ~~wide variety of diffeгent tintеd food items~~. ~~Brilliɑnt colorеd meals gives~~ you ~~plenty of nourishment. 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← Older revision		Revision as of 17:43, 17 January 2014
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	~~56 year~~-~~old Aircraft Maintenance Engineer~~ (~~Components~~ ) ~~Lane from Oak Bluff~~, ~~usually spends time~~ with ~~pursuits~~ for ~~example wind surfing~~, ~~Fat Loss~~ and ~~brewing beer~~. ~~Has toured ever since childhood~~ and ~~has traveled~~ to ~~numerous spots~~, ~~including Ensemble~~ of the ~~Ferrapontov Monastery~~.<br><br>~~Here~~ is ~~my blog~~; ~~4 cycle fat loss solution free download~~ ([~~http:~~//~~wiki~~.~~opennet~~.uz/~~index~~.~~php~~/~~Foydalanuvchi_munozarasi~~:~~TashaBlossevill wiki~~.~~opennet~~.uz])		{{chembox
			\| Verifiedfields = changed
			\| Watchedfields = changed
			\| verifiedrevid = 409649915
			\| Name = Performic acid
			\| ImageFileL1 = Performic-acid-2D-skeletal.svg
			\| ImageSizeL1 = 120px
			\| ImageNameL1 = Skeletal structure of performic acid
			\| ImageFileR1 = Performic-acid-3D-balls.png
			\| ImageSizeR1 = 120px
			\| ImageNameR1 = 3D model of performic acid
			\| IUPACName =
			\| OtherNames = Hydroperoxyformaldehyde, formyl hydroperoxide, methaneperoxic acid, permethanoic acid, peroxyformic acid
			\| Section1 = {{Chembox Identifiers
			\| SMILES = O=COO
			\| UNII_Ref = {{fdacite\|correct\|FDA}}=
			\| UNII =
			\| CASNo = 107-32-4
			\| PubChem = 66051
			\| ChemSpiderID_Ref = {{chemspidercite\|changed\|chemspider}}
			\| ChemSpiderID = 59441
			\| StdInChI_Ref = {{stdinchicite\|changed\|chemspider}}
			\| StdInChI=1S/CH2O3/c2-1-4-3/h1,3H
			\| StdInChIKey_Ref = {{stdinchicite\|changed\|chemspider}}
			\| StdInChIKey = SCKXCAADGDQQCS-UHFFFAOYSA-N
			\| CASNo = 107-32-4
			\| CASNo_Ref = {{cascite\|correct\|??}}
			\| ChEBI_Ref = {{ebicite\|correct\|EBI}}
			\| ChEBI =
			\| RTECS =
			}}
			\| Section2 = {{Chembox Properties
			\| C = 1\|H = 2\|O =3
			\| Appearance = Colorless liquid
			\| Density =
			\| Solubility =
			\| MeltingPt = -18 °C<ref name=u1>Elvers, B. ''et al.'' (ed.) (1991) Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. Vol. A19, Wiley, p. 206</ref>
			\| BoilingPt = 50 °C(13.3 kPa; 90% pure acid)<ref name=u1/>
			\| pKa = 7.1<ref name=u1/><ref>F. A. Carroll [http://books.google.com/books?id=A9tlVETEV5YC&pg=PA416 Perspectives on Structure and Mechanism in Organic Chemistry], Wiley-Interscience, 2010, ISBN 0-470-27610-X p. 416</ref>
			}}
			\| Section3 = {{Chembox Structure
			\| MolShape =
			\| Dipole =
			}}
			\| Section7 = {{Chembox Hazards
			\| ExternalMSDS =
			\| MainHazards =
			\| NFPA-H =
			\| NFPA-F =
			\| NFPA-R =
			\| FlashPt =
			\| RPhrases =
			\| SPhrases =
			}}
			\| Section8 = {{Chembox Related
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			}}

			'''Performic acid''' (PFA) is an [[organic compound]] with the [[chemical formula\|formula]] CH<sub>2</sub>O<sub>3</sub>. It is an unstable colorless liquid which can be produced by mixing [[formic acid]] with [[hydrogen peroxide]]. Owing to its oxidizing and disinfecting action, it is used in the chemical, medical and food industries.

			==Properties and applications==
			Performic acid is a colorless liquid soluble in water, alcohols, [[ether]], [[benzene]], [[chloroform]] and other organic solvents.<ref name=j2/><ref name=b1/> Its strong oxidizing properties are used for cleaving [[disulfide bond]]s in protein mapping,<ref>{{cite journal\|doi=10.1101/pdb.prot4698\|last1=Simpson\|year=2007\|first1=R. J.\|pages=pdb.prot4698\|volume=2007\|journal=Cold Spring Harbor Protocols\|title=Performic Acid Oxidation of Proteins}}</ref> as well as for epoxidation, hydroxylation and oxidation reactions in organic synthesis.<ref name=b1>Pradyot Patnaik [http://books.google.com/books?id=-CRRJBVv5d0C&pg=PA128 A comprehensive guide to the hazardous properties of chemical substances], Wiley-Interscience, 2007, ISBN 0-471-71458-5, p. 128</ref> In the medical and food industries, performic acid is commonly used to disinfect equipment. It is effective against viruses, bacterial spores, [[algae]], microscopic fungi and [[Mycobacterium\|mycobacteria]], as well as other [[microorganism]]s such as [[zooplankton]]. The popularity of performic acid as a sterilizer originates from the safe nature of its degradation products, mostly [[carbon dioxide]], oxygen and water.<ref name=j2/><ref>{{cite journal\|last1=Gehr\|first1=R\|last2=Chen\|first2=D\|last3=Moreau\|first3=M\|title=Performic acid (PFA): tests on an advanced primary effluent show promising disinfection performance\|url=http://www.iwaponline.com/wst/05901/0089/059010089.pdf\|journal=Water science and technology : a journal of the International Association on Water Pollution Research\|volume=59\|issue=1\|pages=89–96\|year=2009\|pmid=19151490\|doi=10.2166/wst.2009.761}}</ref> The disinfecting action of performic acid is also faster than that of the related compounds [[peracetic acid]] and hydrogen peroxide.<ref name=pat2/> The major drawbacks of performic acid are handling dangers related to its high reactivity, as well as instability, especially upon heating, which means that the acid must be used within about 12 hours of it being synthesised.<ref name=pat2/><ref>{{cite journal\|author=Bydzovska, O. and Merka, V. \|year=1981 \|title=Disinfecting Properties of Performic Acid Against Bacteriophage (X 174 as a Model of Small Envelope-free Viruses\|pmid=6459365\|journal=J. Hygiene, Epidemiology Microbiology and Immunology \|volume=25\|issue=4\|pages=414–423}}</ref><ref>{{cite journal\|title=Execution of a Performic Acid Oxidation on Multikilogram Scale\|doi=10.1021/op700039r\|author= Ripin, D.H.B. ''et al.''\|year=2007\|pages=762\|volume=11\|journal=Org. Process Res. Dev.}}</ref>

			==Synthesis==
			Synthesis of pure performic acid has not been reported.<ref name=j2/> Aqueous solutions (up to 90%) can be prepared by mixing 70–98 wt.% of formic acid (in water) with 35–50 wt% of hydrogen peroxide.
			:<math>\rm HCOOH + H_2O_2 \leftrightharpoons HCO_2OH + H_2O</math>

			This reaction is reversible and can be used for large scale industrial production if accelerated with a [[catalyst]]; however, its temperature must be kept below 80–85 °C to avoid an explosion.<ref>Elvers, B. ''et al.'' (ed.) (1991) Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. Vol. A12, Wiley, p. 16</ref> The catalyst can be [[nitric acid\|nitric]], [[hydrofluoric acid\|hydrofluoric]], [[phosphoric acid\|phosphoric]] or [[sulfuric acid]] or their salts;<ref name=j2>{{cite journal\|last1=Swern\|first1=Daniel\|title=Organic Peracids.\|journal=Chemical Reviews\|volume=45\|pages=1\|year=1949\|doi=10.1021/cr60140a001\|quote=In the absence of catalysts, performic acid explodes when heated rapidly to 80–85°C.}}</ref><ref>{{cite journal\|doi=10.1021/ja01201a016\|last1=English\|first1=James\|year=1947\|pages=2120\|volume=69\|journal=Journal of the American Chemical Society\|last2=Gregory\|first2=J. Delafield\|title=Performic Acid Hydroxylation of a,p-Unsaturated Acids and Esters}}</ref> it can also be an organic compound containing at least one [[ester]] group, such as [[carboxylic acid]] [[ester]]<ref>Matilla, T. and Aksela, R. 2000 Method for the Preparation of Aqueous Solutions Containing Performic Acid as Well as Their Use. {{US Patent\|6049002}}, Issue date: April 11, 2000</ref> or peracetic acid.<ref name=pat2>Preuss, A., Fuchs, R., Huss, M. & Schneider, R. 2001 Aqueous Disinfecting Agent Containing Performic Acid and Peracetic Acid Process for Production and Process for Use Thereof {{US Patent\|6211237}}, Issue date: April 3, 2001</ref>

			==Safety==
			Performic acid is non-toxic; it does irritate the skin, but less so than peracetic acid. Concentrated acid (above 50%) is highly reactive; it readily decomposes upon heating, and explodes upon rapid heating to 80–85 °C. It may ignite or explode at room temperature when combined with flammable substances, such as [[formaldehyde]], [[benzaldehyde]], or [[aniline]], and explodes violently upon addition of metal powders.<ref name=j2/> For this reason, spilled performic acid is diluted with cold water and collected with neutral, non-flammable inorganic absorbents, such as [[vermiculite]].<ref name=b1/>

			==References==
			{{Reflist\|2}}

			{{DEFAULTSORT:Performic Acid}}
			[[Category:Peroxy acids]]
			[[Category:Oxidizing agents]]

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